{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,27]],"date-time":"2026-08-27T17:29:56Z","timestamp":1787851796060,"version":"build-2784847793"},"reference-count":36,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,8,27]],"date-time":"2026-08-27T00:00:00Z","timestamp":1787788800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,8,27]],"date-time":"2026-08-27T00:00:00Z","timestamp":1787788800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100000781","name":"European Research Council","doi-asserted-by":"publisher","award":["949087"],"award-info":[{"award-number":["949087"]}],"id":[{"id":"10.13039\/501100000781","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>Living systems maintain functional states through the continuous dissipation of chemical energy, a principle that remains a formidable challenge to replicate in synthetic molecular architectures. In such context, while classical chemiluminescence relies on irreversible bond\u2010breaking events that consume the luminophore, regenerative chemiluminescence (RCL) offers a circular alternative based on electron\u2010transfer cycles. However, traditional RCL remains constrained by harsh operating conditions and requires isolation of reactive intermediates. Here, we report the development of a water\u2010soluble Perylene Bisimide (PBI) scaffold capable of undergoing Chemically Fueled Regenerative Chemiluminescence (CFRCL) under mild, dissipative conditions. By strategically tailoring the PBI core we enable a redox cycle driven by mild chemical fuels, sodium dithionite and hydrogen peroxide, in aqueous media. We show that light production can be sustained and pulsed through continuous chemical fueling. These results bridge the gap between redox\u2010active molecular chemistry and autonomous light\u2010emitting materials, providing a novel non\u2010equilibrium analytical tool and bio\u2010inspired photonic system.<\/jats:p>","DOI":"10.1002\/anie.9467229","type":"journal-article","created":{"date-parts":[[2026,8,27]],"date-time":"2026-08-27T17:15:11Z","timestamp":1787850911000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Dissipative Regenerative Chemiluminescence in Water: A Perylene\u2010Based Out\u2010of\u2010Equilibrium Light\u2010Emitting System"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0007-6995-8902","authenticated-orcid":false,"given":"Luca","family":"Morgan","sequence":"first","affiliation":[{"name":"Dipartimento Di Scienze Chimiche Universit\u00e0 Degli Studi Di Padova  Padova 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Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2385-9833","authenticated-orcid":false,"given":"Sara","family":"Bonacchi","sequence":"additional","affiliation":[{"name":"Dipartimento Di Scienze Chimiche Universit\u00e0 Degli Studi Di Padova  Padova Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2647-9967","authenticated-orcid":false,"given":"Alessandro","family":"Aliprandi","sequence":"additional","affiliation":[{"name":"Dipartimento Di Scienze Chimiche Universit\u00e0 Degli Studi Di Padova  Padova 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