{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T19:02:19Z","timestamp":1788980539201,"version":"build-2803163510"},"reference-count":38,"publisher":"Wiley","issue":"28","license":[{"start":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T00:00:00Z","timestamp":1778803200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T00:00:00Z","timestamp":1778803200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["63263162"],"award-info":[{"award-number":["63263162"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,7,6]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The selective oxidation of methane to value\u2010added oxygenates remains a long\u2010standing challenge in catalysis, often constrained by poor reactivity (and single\u2010pass methane conversion) and limited product selectivity. In this study, we report a Rh\u2010Beta catalyst featuring atomically dispersed Rh\n                    <jats:sup>\u03b4+<\/jats:sup>\n                    species embedded in the aluminosilicate *BEA zeolite matrix that enables highly selective methane oxidation in a CH\n                    <jats:sub>4\u2013<\/jats:sub>\n                    O\n                    <jats:sub>2\u2013<\/jats:sub>\n                    CO\u2013H\n                    <jats:sub>2<\/jats:sub>\n                    O system. This catalyst achieves a remarkable formic acid space\u2010time yield of 210\u00a0mol mol\n                    <jats:sub>Rh<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 7.84% methane conversion, with formic acid selectivity of 96%\u2014surpassing all previously reported catalyst systems. Mechanistic investigations combining spectroscopy and theory reveal that hydroxyl radicals, generated\n                    <jats:italic>via<\/jats:italic>\n                    acid\u2010promoted water\u2010gas shift and in situ H\n                    <jats:sub>2\u2013<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    reactions, are responsible for methane activation, while the zeolite backbone plays a vital role in stabilizing formaldehyde intermediate and promoting its further oxidation to formic acid product. This work offers a new perspective on the conversion\u2013selectivity relationship in methane oxidation and demonstrates a feasible pathway for the selective functionalization of methane under mild conditions.\n                  <\/jats:p>","DOI":"10.1002\/anie.9555228","type":"journal-article","created":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T17:12:31Z","timestamp":1778865151000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Boosting Formic Acid Production in Methane Oxidation by Zeolite Confined Single\u2010Site Rh Catalyst"],"prefix":"10.1002","volume":"65","author":[{"given":"Xin","family":"Deng","sequence":"first","affiliation":[{"name":"Key Laboratory of Advanced Energy Materials Chemistry of Ministry of Education, College of Chemistry Nankai University  Tianjin P.R. 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