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Strategies that mitigate deactivation by weakening the adsorption of poisoning intermediates are constrained by the linear scaling relationships of adsorption energies, which simultaneously reduce the binding of other key reactive species, leading to insufficient catalytic performance or demanding reaction conditions. In this study, we propose and validate a pre\u2010compensation strategy between electronic structure and geometric structure specifically toward Rh active sites to mitigate *NO poisoning in the nitrite electroreduction reaction (NO\n                    <jats:sub>2<\/jats:sub>\n                    ERR). In the fabricated intermetallic RhSb bimetallenes (RhSb IMMs), Sb boosts the adsorption capacity of Rh toward reactants by modulating the electronic structure, compensating for the geometrically constrained weak adsorption configuration imposed by the ordered alloy structure. Consequently, RhSb IMMs operate stably for over 880 h with an outstanding Faradaic efficiency of over 90% at \u22120.3\u00a0V (vs. RHE) and achieve an average ammonia (NH\n                    <jats:sub>3<\/jats:sub>\n                    ) yield rate of 107.5\u00a0g h\n                    <jats:sup>\u22121<\/jats:sup>\n                    g\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    for NO\n                    <jats:sub>2<\/jats:sub>\n                    ERR at a current density exceeding 0.45 A cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . This compensation strategy provides a rational design principle for reconciling fundamental trade\u2010offs in catalysis and beyond.\n                  <\/jats:p>","DOI":"10.1002\/anie.9586956","type":"journal-article","created":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T14:29:47Z","timestamp":1785940187000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Electronic\u2010Geometric Pre\u2010Compensation Enables Intermetallic RhSb Bimetallenes for Efficient Nitrite Electroreduction"],"prefix":"10.1002","volume":"65","author":[{"given":"Wei","family":"Zhong","sequence":"first","affiliation":[{"name":"Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education) Key Laboratory of Macromolecular Science of Shaanxi Province Shaanxi Key Laboratory for Advanced Energy Devices School of Materials Science and Engineering Shaanxi Normal University  Xi'an 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Nonequilibrium Synthesis and Modulation of Condensed Matter School of Physics Xi'an Jiaotong University Xi'an China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6577-5665","authenticated-orcid":false,"given":"Xuan","family":"Ai","sequence":"additional","affiliation":[{"name":"Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education) Key Laboratory of Macromolecular Science of Shaanxi Province Shaanxi Key Laboratory for Advanced Energy Devices School of Materials Science and Engineering Shaanxi Normal University  Xi'an China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Carbon Neutrality Zhejiang Wanli University  Ningbo China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2054-908X","authenticated-orcid":false,"given":"Bao Yu","family":"Xia","sequence":"additional","affiliation":[{"name":"State Key Laboratory of New Textile Materials and Advanced Processing Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education) Hubei Key Laboratory of Material Chemistry and Service Failure School of Chemistry and Chemical Engineering Huazhong University of Science and Technology Wuhan China"},{"name":"Center For Next\u2010Generation Energy Materials and School of Chemical Engineering Sungkyunkwan University (SKKU), Jangan\u2010gu  Suwon Gyeonggi\u2010do Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Chen","sequence":"additional","affiliation":[{"name":"Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education) Key Laboratory of Macromolecular Science of Shaanxi Province Shaanxi Key Laboratory for Advanced Energy Devices School of Materials Science and Engineering Shaanxi Normal University  Xi'an 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