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NiO\n                    <jats:sub>x<\/jats:sub>\n                    \/SAM layers are plagued by disordered molecular packing and inadequate surface coverage, while perovskite films fabricated in air are highly susceptible to oxidative degradation. These issues collectively aggravate interfacial non\u2010radiative recombination and accelerate device degradation. To address these challenges, a phenothiazine (PTZ)\u2010based self\u2010assembled monolayer (SAM) molecule was designed and synthesized to enhance the air\u2010processing efficiency and stability of PSCs. The phosphoric acid functional groups interactions with the NiO\n                    <jats:sub>x<\/jats:sub>\n                    substrate and regulates the valence state of nickel, while the sulfur\u2010containing functional groups on the butterfly\u2010shaped PTZ skeleton effectively passivate uncoordinated lead and improve the crystallization quality of perovskite films. Notably, the Me\u20104PACz\/PTZ1 co\u2010assembly system optimizes the energy band alignment between the SAM and the perovskite layer, and the PTZ moiety simultaneously suppresses the oxidation of iodide ions and formamidinium cations. Consequently, the optimized fully air\u2010processed PSCs deliver a power conversion efficiency (PCE) of 26.1% and demonstrate excellent long\u2010term stability under continuous illumination. This interface engineering strategy enables the fabrication of high\u2010performance, stable PSCs that are compatible with environmentally benign large\u2010scale manufacturing.\n                  <\/jats:p>","DOI":"10.1002\/anie.9607454","type":"journal-article","created":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T04:15:01Z","timestamp":1788927301000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Phenothiazine\u2010Based Self\u2010Assembled Monolayers for Highly Efficient and Stable Full Air\u2010Fabricated Inverted Perovskite Solar Cells"],"prefix":"10.1002","author":[{"given":"Yuchen","family":"Li","sequence":"first","affiliation":[{"name":"Institute of Carbon Neutrality College of Chemical and Biological Engineering Shandong University of Science and Technology  Qingdao P. R. 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