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Among various topological architectures, slide\u2010ring networks and entangled networks have attracted considerable attention, owing to their unique dynamic mobility and spatial interlocked effects, respectively. However, these two topological motifs have so far been explored separately, and their synergistic integration within a single elastomer network remains a significant challenge. Herein, we construct a synergistic topological elastomeric network (\n                    <jats:bold>SEPN<\/jats:bold>\n                    ) by integrating slide\u2010ring and entangled structures through a molecular\u2010level interpenetration\u2212polymerization co\u2010evolution process, followed by aldimine crosslinking and metal\u2010coordination assembly. The resulting network combines the dynamic mobility of slide\u2010ring structures with the spatial interlocked effect of entangled nodes, enabling efficient stress redistribution and energy dissipation. Consequently,\n                    <jats:bold>SEPN<\/jats:bold>\n                    exhibits an exceptional combination of high strength (24.3\u00a0MPa), superior toughness (327\u00a0MJ\/m\n                    <jats:sup>3<\/jats:sup>\n                    ), large extensibility (2540%), and dynamic mechanical adaptability. This work establishes a topological synergy strategy for designing next\u2010generation high\u2010performance elastomeric materials.\n                  <\/jats:p>","DOI":"10.1002\/anie.9631477","type":"journal-article","created":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T10:32:22Z","timestamp":1790677942000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Topological Integration of Slide\u2010Ring and Entangled Networks"],"prefix":"10.1002","author":[{"given":"Yuling","family":"Pan","sequence":"first","affiliation":[{"name":"State Key Laboratory of Soil Pollution Control and Safety Stoddart Institute of Molecular Science Department of Chemistry Zhejiang University  Hangzhou P. R. China"},{"name":"Key Laboratory of High\u2010Performance Adhesion Functional Materials and Application Technology of Zhejiang Zhejiang\u2010Israel Joint Laboratory of Self\u2010Assembling Functional Materials ZJU\u2010Hangzhou Global Scientific and Technological Innovation Center Zhejiang University  Hangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-9047-4057","authenticated-orcid":false,"given":"Liya","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Soil Pollution Control and Safety Stoddart Institute of Molecular Science Department of Chemistry Zhejiang University  Hangzhou P. R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lan","family":"Sheng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Soil Pollution Control and Safety Stoddart Institute of Molecular Science Department of Chemistry Zhejiang University  Hangzhou P. R. China"},{"name":"Key Laboratory of High\u2010Performance Adhesion Functional Materials and Application Technology of Zhejiang Zhejiang\u2010Israel Joint Laboratory of Self\u2010Assembling Functional Materials ZJU\u2010Hangzhou Global Scientific and Technological Innovation Center Zhejiang University  Hangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0647-7251","authenticated-orcid":false,"given":"Wei","family":"You","sequence":"additional","affiliation":[{"name":"Advanced Rheology Institute Department of Polymer Science and Engineering State Key Laboratory of Polyolefins and Catalysis Shanghai Key Laboratory of Catalysis Technology For Polyolefins Shanghai Jiao Tong University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingrui","family":"Xiao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Soil Pollution Control and Safety Stoddart Institute of Molecular Science Department of Chemistry Zhejiang University  Hangzhou P. R. 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