{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,2]],"date-time":"2026-11-02T23:28:11Z","timestamp":1793662091475,"version":"4.5.1"},"reference-count":76,"publisher":"Wiley","issue":"41","license":[{"start":{"date-parts":[[2026,8,8]],"date-time":"2026-08-08T00:00:00Z","timestamp":1786147200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,8]],"date-time":"2026-08-08T00:00:00Z","timestamp":1786147200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,10,5]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Aqueous Zn\u2013S batteries (AZSBs) have garnered significant attention owing to their high energy density and low cost. However, their practical application is hindered by the limited electrochemical reversibility of sulfur cathode and the interfacial instability of zinc anode. Here, we developed a functionalized co\u2010solvent electrolyte incorporating aprotic polar tetramethylurea (TMU) and potassium iodide (KI) as synergistic additives, where TMU regulates the Zn\n                    <jats:sup>2+<\/jats:sup>\n                    coordination environment and cooperates with iodide species to construct an electrolyte\u2010derived, interface\u2010confined, and coordination\u2010mediated dynamic ion bridge pathway. This pathway couples TMU\u2010regulated Zn\n                    <jats:sup>2+<\/jats:sup>\n                    transport with I\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    \/I\n                    <jats:sup>\u2212<\/jats:sup>\n                    \u2010mediated charge transfer at the sulfur cathode interface, thereby reducing the kinetic barriers for Zn\n                    <jats:sup>2+<\/jats:sup>\n                    transport and ZnS conversion. Meanwhile, the TMU\/KI\u2010regulated interfacial environment homogenizes Zn\n                    <jats:sup>2+<\/jats:sup>\n                    flux at the anode, promotes uniform Zn plating\/stripping, and suppresses parasitic reactions. Through the synergistic regulation of the ion bridge, the AZSB delivers a high specific capacity of 759 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 5 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and maintains over 71.2% capacity retention after 1000 cycles. This work proposes a promising electrolyte design strategy for energetic AZSBs via synergistic regulation, offering a promising route toward next\u2010generation sustainable energy storage systems.\n                  <\/jats:p>","DOI":"10.1002\/anie.9631813","type":"journal-article","created":{"date-parts":[[2026,8,8]],"date-time":"2026-08-08T11:03:02Z","timestamp":1786186982000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Ion Bridging Enables Dual\u2010Interface Engineering for High Capacity and Long Cycling Aqueous Zinc\u2013Sulfur Battery"],"prefix":"10.1002","volume":"65","author":[{"given":"Boao","family":"Wanyan","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shaoxing University  Shaoxing Zhejiang P. R. China"},{"name":"School of Materials Science and Chemical Engineering Ningbo University  Ningbo Zhejiang P. R. China"},{"name":"School of Advanced Materials Peking University Shenzhen Graduate School  Shenzhen Guangdong P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1218-1895","authenticated-orcid":false,"given":"Xiang","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shaoxing University  Shaoxing Zhejiang P. R. China"},{"name":"School of Materials Science and Chemical Engineering Ningbo University  Ningbo Zhejiang P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiahe","family":"Geng","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shaoxing University  Shaoxing Zhejiang P. R. China"},{"name":"School of Materials Science and Chemical Engineering Ningbo University  Ningbo Zhejiang P. R. 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