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Crystalline coordination materials provide unique opportunities for investigating coordination phenomena because their long\u2010range structural order enables atomic\u2010resolution characterization of coordination environments and structure\u2013property relationships. Among them, metal\u2013organic frameworks have greatly expanded the scope of coordination chemistry through their highly tunable compositions and spatial arrangements. To simplify the complexity associated with framework construction, post\u2010synthetic modification has emerged as an effective strategy for systematically tailoring existing frameworks while preserving their networks. Nevertheless, conventional modification approaches remain limited in installation efficiency and coordination investigation. The discovery of PCN\u2010700 together with the linker installation strategy has largely overcome these limitations. Owing to its highly uncoordinated zirconium clusters, predefined installation sites, and exceptional framework flexibility, PCN\u2010700 enables efficient installation while maintaining crystallinity, allowing atomic\u2010resolution visualization. Besides, linker installation decouples coordination from crystallization, transforming framework construction into controllable events at predefined crystallographic sites. In this review, we discuss linker installation pathways, host\u2013guest interactions, and structure\u2010enabled applications in PCN\u2010700, highlighting the role of linker installation in establishing PCN\u2010700 as a model system for elucidating fundamental coordination chemistry, quantitatively correlating coordination events with material properties, and guiding the rational design of functional materials.<\/jats:p>","DOI":"10.1002\/anie.9641173","type":"journal-article","created":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T12:17:33Z","timestamp":1790425053000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["PCN\u2010700: A Model Platform for Crystallographic Probing of Coordination Behavior in Metal\u2013Organic 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