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However, the conventional hybrid LRCT\u2010SRCT strategy proves less effective in enhancing the performance of deep\u2010blue emitters. In this study, we propose a novel triple\u2010LRCT\u2010channel strategy to markedly enhance spin\u2010orbit coupling (SOC) interactions in deep\u2010blue LRCT\/SRCT type TADF emitters. Based on the pronounced differentiation among the excited states enabled by this strategy, the proof\u2010of\u2010concept emitter\n                    <jats:bold>DABNA\u2010CN\u2010PXZ<\/jats:bold>\n                    exhibits multiple RISC channels, resulting in a tenfold faster RISC rate than its MR prototype. The corresponding device achieves a high maximum external quantum efficiency of 24.4% and a narrow FWHM of 24\u00a0nm, which ranks among the lowest reported for boron\u2010nitrogen\u2010based LRCT\/SRCT type TADF emitters, arising from the judicious selection of substituents in\n                    <jats:bold>DABNA\u2010CN\u2010PXZ<\/jats:bold>\n                    that enables precise control over molecular rigidity and LRCT characteristics. These results demonstrate that\n                    <jats:bold>DABNA\u2010CN\u2010PXZ<\/jats:bold>\n                    is among the purest deep\u2010blue LRCT\/SRCT type TADF emitters, delivering excellent device performance under BT.2020\u2010compliant conditions and thus validating the superiority of our molecular design strategy.\n                  <\/jats:p>","DOI":"10.1002\/anie.9652615","type":"journal-article","created":{"date-parts":[[2026,4,6]],"date-time":"2026-04-06T03:16:48Z","timestamp":1775445408000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Triple Long\u2010Range Charge\u2010Transfer Channels Enable Efficient LRCT\/SRCT Hybridization in Narrowband Deep\u2010Blue TADF Emission"],"prefix":"10.1002","volume":"65","author":[{"given":"Shan","family":"Huang","sequence":"first","affiliation":[{"name":"Wuhan National Laboratory For Optoelectronics School of Optical and Electronic Information Huazhong University of Science and Technology Wuhan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ben","family":"Chen","sequence":"additional","affiliation":[{"name":"Wuhan National Laboratory For Optoelectronics School of Optical and Electronic Information Huazhong University of Science and Technology Wuhan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Yan","sequence":"additional","affiliation":[{"name":"Wuhan National Laboratory For Optoelectronics School of Optical and Electronic Information Huazhong University of Science and Technology Wuhan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hanrui","family":"Su","sequence":"additional","affiliation":[{"name":"Wuhan National Laboratory For Optoelectronics School of Optical and Electronic Information Huazhong University of Science and Technology Wuhan P. R. 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