{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T21:44:43Z","timestamp":1792014283846,"version":"4.4.0"},"reference-count":61,"publisher":"Wiley","issue":"23","license":[{"start":{"date-parts":[[2026,4,17]],"date-time":"2026-04-17T00:00:00Z","timestamp":1776384000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,4,17]],"date-time":"2026-04-17T00:00:00Z","timestamp":1776384000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U22A20140"],"award-info":[{"award-number":["U22A20140"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,6,1]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Rechargeable aqueous Zn||I\n                    <jats:sub>2<\/jats:sub>\n                    batteries have received significant attention for the high energy density, inherent safety, and ecological friendliness. However, the sluggish iodine redox kinetics and the formation of highly soluble polyiodide (I\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    and I\n                    <jats:sub>5<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) seriously affect the rate capability and cycling stability of Zn||I\n                    <jats:sub>2<\/jats:sub>\n                    battery. Herein, ZrB\n                    <jats:sub>2<\/jats:sub>\n                    is synthesized as a catalyst host for polyiodide conversion, where unsaturated surface Zr atoms provide Lewis\u2010acid sites that enable strong interaction with polyiodide species. These sites not only confine polyiodide anions through strong adsorption to suppress polyiodide shuttling, but also catalyze their stepwise conversion from I\n                    <jats:sup>\u2212<\/jats:sup>\n                    to I\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    and further to I\n                    <jats:sub>2<\/jats:sub>\n                    during charging, thereby reducing the energy barrier and improving iodine utilization. Consequently, the Zn||I\n                    <jats:sub>2<\/jats:sub>\n                    @ZrB\n                    <jats:sub>2<\/jats:sub>\n                    \/AC full cell displays remarkable rate performance, retaining 80.5% of the capacity as the current density increases from 1 to 10\u00a0A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Remarkably, the full cells exhibit exceptionally long cycle life of 50,000 cycles with negligible capacity decay. The Zn||I\n                    <jats:sub>2<\/jats:sub>\n                    @ZrB\n                    <jats:sub>2<\/jats:sub>\n                    \/AC pouch cell with a high I\n                    <jats:sub>2<\/jats:sub>\n                    mass loading of 33\u00a0mg cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    maintains a stable capacity of 1.2\u00a0Ah over 600 cycles (more than 1400\u00a0h).\n                  <\/jats:p>","DOI":"10.1002\/anie.9794577","type":"journal-article","created":{"date-parts":[[2026,4,18]],"date-time":"2026-04-18T04:00:01Z","timestamp":1776484801000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Efficient I\n                    <sup>\u2212<\/sup>\n                    \/I\n                    <sub>3<\/sub>\n                    <sup>\u2212<\/sup>\n                    \/I\n                    <sub>2<\/sub>\n                    Conversion and Shuttle\u2010Suppression in High\u2010Rate Ah\u2010Level Zinc\u2010Iodine Batteries Enabled by Bifunctional Confined\u2010Catalyst ZrB\n                    <sub>2<\/sub>\n                    \/AC Host"],"prefix":"10.1002","volume":"65","author":[{"given":"Chuanlin","family":"Li","sequence":"first","affiliation":[{"name":"School of Physics and Technology University of Jinan  Jinan Shandong P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Min","sequence":"additional","affiliation":[{"name":"School of Physics and Technology University of Jinan  Jinan Shandong P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xixi","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Physics and Technology University of Jinan  Jinan Shandong P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shunshun","family":"Zhao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing Key Laboratory of Electrochemical Process and Technology of Materials Beijing University of Chemical Technology  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guangmeng","family":"Qu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shandong University  Jinan Shandong P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qingxiu","family":"Yu","sequence":"additional","affiliation":[{"name":"School of Physics and Technology University of Jinan  Jinan Shandong P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingxiang","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Physics and Technology University of Jinan  Jinan Shandong P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dongbo","family":"Yuan","sequence":"additional","affiliation":[{"name":"School of Physics and Technology University of Jinan  Jinan Shandong P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3877-6483","authenticated-orcid":false,"given":"Xijin","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Physics and Technology University of Jinan  Jinan Shandong P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,4,17]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.372.6545.890"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201058153\u20102"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202513389"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202515633"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202422036"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202413990"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202411884"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE00075K"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010024\u201001515\u20109"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE00365B"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.4c00992"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202302187"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202403187"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202408317"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2016.33"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202600044"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202502563"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2024.05.022"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202423265"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202506822"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CP02205F"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CP03349F"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4SC00276H"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202210043"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202312246"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c09445"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE00809C"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202418942"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.3c02062"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2020.146763"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.vacuum.2023.112199"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202203391"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2020.146201"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.physleta.2024.129606"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3SC06150G"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scib.2021.10.011"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202300922"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/inf2.12620"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202422163"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE01639K"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202416235"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201044532\u20100"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2024.11.026"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE04372C"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202422036"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE05140H"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c16932"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2022.05.005"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.4c02930"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE00500G"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202201716"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202421714"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202506849"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202006897"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202314189"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202420221"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2023.142923"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202014447"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c21026"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202419502"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202501049"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.9794577","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.9794577","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.9794577","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,27]],"date-time":"2026-08-27T18:16:32Z","timestamp":1787854592000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.9794577"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,4,17]]},"references-count":61,"journal-issue":{"issue":"23","published-print":{"date-parts":[[2026,6,1]]}},"alternative-id":["10.1002\/anie.9794577"],"URL":"https:\/\/doi.org\/10.1002\/anie.9794577","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,4,17]]},"assertion":[{"value":"2025-12-03","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-03-24","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-04-17","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e9794577"}}