{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T15:45:10Z","timestamp":1792079110086,"version":"4.4.0"},"reference-count":49,"publisher":"Wiley","issue":"36","license":[{"start":{"date-parts":[[2026,7,3]],"date-time":"2026-07-03T00:00:00Z","timestamp":1783036800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,7,3]],"date-time":"2026-07-03T00:00:00Z","timestamp":1783036800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["51925206"],"award-info":[{"award-number":["51925206"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52461160328"],"award-info":[{"award-number":["52461160328"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["20720220009"],"award-info":[{"award-number":["20720220009"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["WK2490000002"],"award-info":[{"award-number":["WK2490000002"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["RS\u20102023\u201000221668"],"award-info":[{"award-number":["RS\u20102023\u201000221668"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["RS\u20102024\u201000466616"],"award-info":[{"award-number":["RS\u20102024\u201000466616"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["RS\u20102024\u201000435493"],"award-info":[{"award-number":["RS\u20102024\u201000435493"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013461","name":"Anhui Normal University","doi-asserted-by":"publisher","award":["114022303"],"award-info":[{"award-number":["114022303"]}],"id":[{"id":"10.13039\/501100013461","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012692","name":"K. C. Wong Education Foundation","doi-asserted-by":"publisher","award":["GJTD\u20102020\u201015"],"award-info":[{"award-number":["GJTD\u20102020\u201015"]}],"id":[{"id":"10.13039\/501100012692","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,9,1]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Phosphorene is a promising two\u2010dimensional semiconductor for solar\u2010driven redox reactions, yet its practical deployment is severely restricted by rapid degradation under ambient conditions. Conventional covalent functionalization typically forms phosphorus\u2013carbon single bonds (P\u2500C), leaving phosphorus atoms in a four\u2010coordinate environment and thus failing to fully quench the intrinsic reactivity associated with one residual unpaired electron. Here, we develop a selective strategy to achieve five\u2010coordinate passivation of phosphorene by constructing phosphorus\u2013carbon double bonds (P\u2550C) through a one\u2010step photochemical carbene addition reaction. Using a carbene precursor, adamantane groups are grafted onto phosphorene to afford a robust P\u2550C\u2010bonded architecture. Comprehensive spectroscopic analyses, together with density functional theory (DFT) calculations, validate the preferential formation of the P\u2550C bonds. The resulting P\u2550C\u2010passivated phosphorene exhibits markedly improved ambient stability compared to the pristine and four\u2010coordinate\u2010passivated phosphorene. When utilized as a metal\u2010free photocatalyst, the P\u2550C\u2010passivated phosphorene enables highly efficient overall water splitting without sacrificial agents under visible light, delivering record\u2010high evolution of H\n                    <jats:sub>2<\/jats:sub>\n                    and H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    with rates of up to 612 and 658\u00a0\u00b5mol h\n                    <jats:sup>\u22121<\/jats:sup>\n                    g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , respectively, along with excellent cycling stability.\n                  <\/jats:p>","DOI":"10.1002\/anie.9859942","type":"journal-article","created":{"date-parts":[[2026,7,3]],"date-time":"2026-07-03T17:09:46Z","timestamp":1783098586000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Boosting Photocatalytic Overall Water Splitting Activity of Phosphorene Through Five\u2010Coordinate Passivation Enabled by Carbene Addition"],"prefix":"10.1002","volume":"65","author":[{"given":"He","family":"Zhang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Precision and Intelligent Chemistry Collaborative Innovation Center of Chemistry for Energy Materials (<i>i<\/i>ChEM) School of Chemistry and Materials Science University of Science and Technology of China  Hefei China"},{"name":"Department of Energy and Chemical Engineering Center For Dimension\u2010Controllable Organic Frameworks Ulsan National Institute of Science and Technology  Ulsan South\u00a0Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanbo","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Precision and Intelligent Chemistry Collaborative Innovation Center of Chemistry for Energy Materials (<i>i<\/i>ChEM) School of Chemistry and Materials Science University of Science and Technology of China  Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junchi","family":"Xu","sequence":"additional","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science University of Science and Technology of China  Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shengkun","family":"Liu","sequence":"additional","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science University of Science and Technology of China  Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Taotao","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Precision and Intelligent Chemistry Collaborative Innovation Center of Chemistry for Energy Materials (<i>i<\/i>ChEM) School of Chemistry and Materials Science University of Science and Technology of China  Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0777-591X","authenticated-orcid":false,"given":"Chao","family":"Gao","sequence":"additional","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science University of Science and Technology of China  Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2715-0979","authenticated-orcid":false,"given":"Pingwu","family":"Du","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Precision and Intelligent Chemistry Collaborative Innovation Center of Chemistry for Energy Materials (<i>i<\/i>ChEM) School of Chemistry and Materials Science University of Science and Technology of China  Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2851-9878","authenticated-orcid":false,"given":"Hengxing","family":"Ji","sequence":"additional","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science University of Science and Technology of China  Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6116-5605","authenticated-orcid":false,"given":"Jun","family":"Jiang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Precision and Intelligent Chemistry Collaborative Innovation Center of Chemistry for Energy Materials (<i>i<\/i>ChEM) School of Chemistry and Materials Science University of Science and Technology of China  Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9287-532X","authenticated-orcid":false,"given":"Guan\u2010Wu","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Molecular Solids Ministry of Education Anhui Laboratory of Molecule\u2010Based Materials, School of Chemistry and Materials Science Anhui Normal University  Wuhu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1995-8257","authenticated-orcid":false,"given":"Yujie","family":"Xiong","sequence":"additional","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science University of Science and Technology of China  Hefei China"},{"name":"Key Laboratory of Functional Molecular Solids Ministry of Education Anhui Laboratory of Molecule\u2010Based Materials, School of Chemistry and Materials Science Anhui Normal University  Wuhu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4785-2326","authenticated-orcid":false,"given":"Jong\u2010Beom","family":"Baek","sequence":"additional","affiliation":[{"name":"Department of Energy and Chemical Engineering Center For Dimension\u2010Controllable Organic Frameworks Ulsan National Institute of Science and Technology  Ulsan South\u00a0Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6931-9613","authenticated-orcid":false,"given":"Shangfeng","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Precision and Intelligent Chemistry Collaborative Innovation Center of Chemistry for Energy Materials (<i>i<\/i>ChEM) School of Chemistry and Materials Science University of Science and Technology of China  Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,3]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010022\u201005610\u20103"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010021\u201003701\u20101"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2016.61"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/lpor.202400777"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4299"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201705012"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.4c00251"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2505"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010018\u201006437\u20101"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201813218"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201705722"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7NR06085H"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202016033"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10853-022-07678-8"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.18940270152"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.3891\/acta.chem.scand.15\u20100438"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja01490a066"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00518a007"},{"key":"e_1_2_8_20_1","first-page":"259","article-title":"Double Bonds between Phosphorus and Carbon","volume":"33","author":"Appel R.","year":"1989","journal-title":"Advances in Inorganic Chemistry"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202005815"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/c9pp00124g"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl501617j"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19550881231"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00095a049"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9NJ04757C"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2021.12.046"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8QM00237A"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1238\/Physica.Topical.115a00548"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aav5842"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202407551"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/pssb.201600437"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.4975062"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.59.1327"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.5b01297"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b08416"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202302919"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202008514"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201906416"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198707761"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1088\/1361-648X\/ab7fd8"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.8b00521"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201605776"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201804770"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/inf2.12219"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/prechem.4c00035"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202311352"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160\u2010023\u201000272\u2010z"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/prechem.3c00096"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaa3145"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.9859942","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.9859942","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.9859942","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T14:53:15Z","timestamp":1792075995000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.9859942"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,3]]},"references-count":49,"journal-issue":{"issue":"36","published-print":{"date-parts":[[2026,9,1]]}},"alternative-id":["10.1002\/anie.9859942"],"URL":"https:\/\/doi.org\/10.1002\/anie.9859942","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,3]]},"assertion":[{"value":"2026-01-25","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-18","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-03","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e9859942"}}