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This represents the strongest intermolecular spin\u2010spin interaction reported to date among cyanidemetallates. When exposed to 470 nm light, this compound exhibits a near\u2010infrared emission with a peak at 763 nm originating from the ligand\u2010to\u2010metal charge\u2010transfer excited state of [W\n                    <jats:sup>V<\/jats:sup>\n                    (CN)\n                    <jats:sub>8<\/jats:sub>\n                    ]\n                    <jats:sup>3\u2212<\/jats:sup>\n                    . Such emission is notably rare for d\n                    <jats:sup>1<\/jats:sup>\n                    metal complexes. Additionally, the noncentrosymmetric crystal structure of this compound enables second harmonic generation, emitting second harmonic light at 650 nm when irradiated with 1300 nm incident light.\n                  <\/jats:p>","DOI":"10.1002\/anie.9994402","type":"journal-article","created":{"date-parts":[[2026,5,12]],"date-time":"2026-05-12T11:19:33Z","timestamp":1778584773000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Glycine\u2010Induced Unique Crystal Packing of Octacyanidetungstates With Strong Intermolecular Antiferromagnetic Interaction, Near\u2010Infrared Emission, and Second Harmonic Generation"],"prefix":"10.1002","volume":"65","author":[{"given":"Tatsuya","family":"Konishi","sequence":"first","affiliation":[{"name":"Department of Chemistry School of Science The University of Tokyo  Tokyo Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5946-944X","authenticated-orcid":false,"given":"Koji","family":"Nakabayashi","sequence":"additional","affiliation":[{"name":"Department of Chemistry School of Science The University of Tokyo  Tokyo Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kunal","family":"Kumar","sequence":"additional","affiliation":[{"name":"Department of Chemistry School of Science The University of Tokyo  Tokyo Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Takeshi","family":"Suzuki","sequence":"additional","affiliation":[{"name":"Institute for Solid State Physics The University of Tokyo  Kashiwa Chiba Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kozo","family":"Okazaki","sequence":"additional","affiliation":[{"name":"Institute for Solid State Physics The University of Tokyo  Kashiwa Chiba Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Masataka","family":"Kobayashi","sequence":"additional","affiliation":[{"name":"Institute for Solid State Physics The University of Tokyo  Kashiwa Chiba Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hidefumi","family":"Akiyama","sequence":"additional","affiliation":[{"name":"Institute for Solid State Physics The University of Tokyo  Kashiwa Chiba Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kouji","family":"Chiba","sequence":"additional","affiliation":[{"name":"Material Science Div. 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