{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T17:57:39Z","timestamp":1791309459735,"version":"4.3.1"},"reference-count":54,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2025,5,25]],"date-time":"2025-05-25T00:00:00Z","timestamp":1748131200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001321","name":"National Research Foundation","doi-asserted-by":"publisher","award":["91230"],"award-info":[{"award-number":["91230"]}],"id":[{"id":"10.13039\/501100001321","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Analytical Science Advances"],"published-print":{"date-parts":[[2025,6]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>The extensive use or misuse of broad\u2010spectrum antibiotics such as penicillins and their existence in various water bodies is still one of increasing global concern due to their persistent nature, which could potentially lead to human health and environmental risks. Recycling or upcycling plastic waste to value\u2010added products such as metal\u2010organic frameworks (MOF) to solve other environmental problems, such as water pollution, has received more attention. As a result, UiO\u201066(Zr)\u2010MOF derived from recycled waste PET bottles (PET\u2010derived UiO\u201066(Zr)\u2010MOF) was investigated for enrichment and removal of amoxicillin (AMX) and penicillin G (PNG) in water bodies. The synthesised adsorbent was characterised using different analytical characterisation techniques. UiO\u201066(Zr)\u2010MOF produced the maximum adsorption capacities of 139 and 147\u00a0mg\/g for AMX and PNG, respectively. Freundlich and pseudo\u2010second\u2010order kinetics models best explained the adsorption process. The dispersive micro\u2010solid phase extraction (D\u2010\u03bc\u2010SPE) of the target analytes was performed using a high\u2010performance liquid chromatography\u2010diode array detector (HPLC\u2010DAD). The effectiveness of the developed method was confirmed by its remarkable analytical performances, such as limits of detection (0.19\u20130.21\u00a0\u00b5g\/L) while the linear range was 0.6\u20131000\u00a0\u00b5g\/L. The feasibility and applicability of the validated UiO\u201066(Zr)\u2010MOF\u2010D\u2010\u03bc\u2010SPE\/HPLC\u2010DAD method were confirmed by applying it in real water analysis. The AMX and PNG were detected in wastewater samples in the ranges of 1.51\u20134.71\u00a0\u00b5g\/L and 0.195\u20131.19\u00a0\u00b5g\/L for influent and effluent. The spike recoveries ranged from 89.9% to 101%, while the precision (intraday and interday) of the method was less than 5%.<\/jats:p>","DOI":"10.1002\/ansa.70023","type":"journal-article","created":{"date-parts":[[2025,5,26]],"date-time":"2025-05-26T00:41:19Z","timestamp":1748220079000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Waste PET Plastic\u2010Derived UIO\u201066(Zr)\u2010MOF Adsorbent for Dispersive Solid Phase Extraction and Removal of Penicillin Antibiotics Water Systems"],"prefix":"10.1002","volume":"6","author":[{"given":"Inga","family":"Skans","sequence":"first","affiliation":[{"name":"Department of Chemical Sciences University of Johannesburg, Doornfontein Campus  Doornfontein South Africa"},{"name":"Department of Science Technology and Innovation\u2010National Research Foundation South African Research Chair Initiative (DSTI\u2010NRF SARChI) in Nanotechnology for Water University of Johannesburg Doornfontein South Africa"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mthokozisi","family":"Mnguni","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences University of Johannesburg, Doornfontein Campus  Doornfontein South Africa"},{"name":"Department of Science Technology and Innovation\u2010National Research Foundation South African Research Chair Initiative (DSTI\u2010NRF SARChI) in Nanotechnology for Water University of Johannesburg Doornfontein South Africa"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7615-0548","authenticated-orcid":false,"given":"Philiswa Nosizo","family":"Nomngongo","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences University of Johannesburg, Doornfontein Campus  Doornfontein South Africa"},{"name":"Department of Science Technology and Innovation\u2010National Research Foundation South African Research Chair Initiative (DSTI\u2010NRF SARChI) in Nanotechnology for Water University of Johannesburg Doornfontein South Africa"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,5,25]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.prevetmed.2020.105151"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2018.06.058"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1007\/s15010\u2010022\u201001842\u20107"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2023.165681"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2023.165681"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.microc.2022.108217"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envres.2020.110664"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.138759"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2023.136725"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2024.174236"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-12-820054-4.00012-4"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.arabjc.2020.07.020"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.17159\/0379\u20104350\/2021\/v75a11"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.microc.2022.108165"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jfca.2023.105944"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2022.136887"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.talo.2023.100185"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.teac.2020.e00109"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.microc.2020.104605"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.3390\/magnetochemistry9050132"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.microc.2024.111239"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.3389\/fenvc.2021.703961"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11696\u2010021\u201001903\u20105"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2024.465192"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.214107"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2017.08.015"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2017.03.004"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2016.07.047"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceja.2023.100581"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.gee.2023.01.002"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.surfin.2024.104494"},{"key":"e_1_2_9_33_1","doi-asserted-by":"crossref","unstructured":"D.Kogolev E.Kurtsevich M.Fatkullin et\u00a0al. \u201cPET Functional Upcycling Through Surface\u2010Assisted Growth of Ni\u2010BDC MOFs and Laser\u2010Induced Carbonization Towards Bend Resistive Sensor \u201d preprint ChemRxiv October 20 2023 https:\/\/doi.org\/10.26434\/chemrxiv\u20102023\u201094j3x.","DOI":"10.26434\/chemrxiv-2023-94j3x"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2022.134845"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2021.130997"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.susmat.2016.10.001"},{"key":"e_1_2_9_37_1","unstructured":"S. K.Selahle \u201cDesign of Nanostructured Material for Sorbent Based Microextraction Combined With Chromatographic Techniques for Analysis of Emerging Pollutants in Water\u201d (PhD diss. University of Johannesburg 2021) https:\/\/hdl.handle.net\/10210\/499156."},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cherd.2024.04.040"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2021.106087"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1080\/26395940.2023.2222910"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598\u2010023\u201034031\u2010z"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.8b00157"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1515\/pac\u20102014\u20101117"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1080\/26395940.2023.2222910"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11144\u2010022\u201002159\u20100"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598\u2010023\u201049393\u20107"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jtice.2019.08.009"},{"key":"e_1_2_9_48_1","unstructured":"N. J.Waleng \u201cMagnetic Polymer Based Composites for Preconcentration and Removal of Selected Neonicotinoid Insecticides\u201d (master's thesis University of Johannesburg 2020) https:\/\/hdl.handle.net\/10210\/458700."},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.partic.2021.04.012"},{"key":"e_1_2_9_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.microc.2023.109053"},{"key":"e_1_2_9_51_1","doi-asserted-by":"publisher","DOI":"10.22126\/anc.2019.3252.1004"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2015.05.043"},{"key":"e_1_2_9_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2021.462677"},{"key":"e_1_2_9_54_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00604\u2010020\u201004605\u2010z"},{"key":"e_1_2_9_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2018.11.069"}],"container-title":["Analytical Science Advances"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/ansa.70023","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T18:08:22Z","timestamp":1759946902000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/ansa.70023"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,5,25]]},"references-count":54,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2025,6]]}},"alternative-id":["10.1002\/ansa.70023"],"URL":"https:\/\/doi.org\/10.1002\/ansa.70023","archive":["Portico"],"relation":{},"ISSN":["2628-5452","2628-5452"],"issn-type":[{"value":"2628-5452","type":"print"},{"value":"2628-5452","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,5,25]]},"assertion":[{"value":"2025-02-27","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-05-02","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-05-25","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e70023"}}