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Here, we report the entrapment and\/or direct synthesis of reactive Fe and Fe\/Pd nanoparticles (about 40\u201370 nm) in a temperature responsive hydrogel network (<jats:italic>N<\/jats:italic>\u2010isopropylacrylamide (NIPAAm), and NIPAAm\u2014PAA). These nanoparticles are stabilized in the hydrogel network and the dechlorination (using trichloroethylene, TCE, as a model compound) reactivity in water is enhanced and controllable in the temperature range of 30\u201334\u00b0C involving polymer domain transitions at lower critical solution temperature (LCST) from hydrophilic to collapsed hydrophobic state. Water fraction modulation of the network and the enhancement of pollutant partitioning by the thermally responsive polymers play an important role in the catalytic activity. \u00a9 2012 Wiley Periodicals, Inc. J. Appl. Polym. 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