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The tensile properties including tensile strength and modulus of membranes with an addition of 1.0 wt % NaCl increased from 2.51 to 4.22 MPa and 33.0 to 176.30 MPa, respectively, more than 160 and 700% of those of the electrospun pure PVA membranes. Moreover, thermogravimetric analysis showed that the initial decomposition temperature (<jats:italic>T<jats:sub>i<\/jats:sub><\/jats:italic>) and the half decomposing temperature (<jats:italic>T<\/jats:italic><jats:sub>50%<\/jats:sub>) of PVA nanofibers with the addition of NaCl were at least 26 and 59\u2009\u00b0C higher than that of pure PVA nanofibers, respectively, indicating a strong interaction between the PVA and the salt ions. \u00a9 2017 Wiley Periodicals, Inc. J. Appl. Polym. 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