{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,16]],"date-time":"2025-10-16T20:08:01Z","timestamp":1760645281812},"reference-count":27,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2006,9,23]],"date-time":"2006-09-23T00:00:00Z","timestamp":1158969600000},"content-version":"vor","delay-in-days":13779,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Archiv der Pharmazie"],"published-print":{"date-parts":[[1969,1]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Bei der Gattermannschen Aldehydsynthese kann der Einsatz von Blaus\u00e4ure durch Verwendung von s\u2010Triazin (I) umgangen werden. Unter Mitwirkung von Halogenwasserstoff bildet sich durch den elektrophilen Eingriff des s\u2010Triazinringes (VIII) in eine Carbanionstruktur (VII) das Aldiminhydrochlorid (XII), das dann in konventioneller Weise zum Aldehyd (XVII) hydrolysiert werden kann. Sehr reaktionsf\u00e4hige Aromaten, wie Furane (VI), Pyrrole (XVIII), Indole (XX) und bestimmte Polyhydroxy\u2010benzole (XXIIa, XXIIb und XXIId) reagieren mit I bereits bei Raumtemperatur ohne Mitwirkung eines Katalysators. Dahingegen bedarf die Synthese von Phenol\u00e4theraldehyden (XXIIIf\u2010\u2010XXIIIk), Ketonaldehyden (XXIIIl und XXIIIm) und Aldehyden kondensierter Ringsysteme (XXV und XXVIII) der Gegenwart eines Friedel\u2010Crafts\u2010Katalysators.<\/jats:p>","DOI":"10.1002\/ardp.19693021107","type":"journal-article","created":{"date-parts":[[2006,10,17]],"date-time":"2006-10-17T00:43:28Z","timestamp":1161045808000},"page":"828-838","source":"Crossref","is-referenced-by-count":15,"title":["Die blaus\u00e4urefreie Durchf\u00fchrung der Gattermannschen Aldehydsynthese"],"prefix":"10.1002","volume":"302","author":[{"given":"A.","family":"Kreutzberger","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2006,9,23]]},"reference":[{"key":"e_1_2_1_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.189803101210"},{"key":"e_1_2_1_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.18980310281"},{"key":"e_1_2_1_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01663a020"},{"key":"e_1_2_1_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01850a093"},{"key":"e_1_2_1_5_2","doi-asserted-by":"publisher","DOI":"10.1007\/BFb0051921"},{"key":"e_1_2_1_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/ardp.19662991203"},{"key":"e_1_2_1_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/ardp.19662991102"},{"key":"e_1_2_1_8_2","first-page":"196","volume":"24","author":"Alessandri L.","year":"1915","journal-title":"Atti Reale Accad. naz. 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