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Silver(I) carbene complexes are synthesized by the reaction of the corresponding benzimidazolium salts with Ag<jats:sub>2<\/jats:sub>O in dichloromethane. These new NHC precursors and Ag\u2013NHC complexes were characterized by spectroscopy techniques and also screened for their antibacterial activities against the standard bacterial strains <jats:italic>Escherichia coli<\/jats:italic>, <jats:italic>Pseudomonas aeruginosa<\/jats:italic>, <jats:italic>Acinetobacter baumannii<\/jats:italic>, <jats:italic>Klebsiella pneumoniae<\/jats:italic>, <jats:italic>Staphylococcus aureus<\/jats:italic>, methicillin\u2010resistant <jats:italic>Staphylococcus aureus<\/jats:italic>, and <jats:italic>Enterococcus faecalis<\/jats:italic>, and the standard fungal strains <jats:italic>Candida albicans<\/jats:italic> and <jats:italic>Candida glabrata<\/jats:italic>, and promising results were achieved. 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