{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T03:03:54Z","timestamp":1789527834702,"version":"build-2803163510"},"reference-count":73,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2006,9,8]],"date-time":"2006-09-08T00:00:00Z","timestamp":1157673600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2006,10,20]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The reaction of cadmium(II) perchlorate with urocanic acid under different conditions created three novel coordination compounds: [Cd<jats:sub>2<\/jats:sub>(L<jats:sup>2<\/jats:sup>)<jats:sub>2<\/jats:sub>\u2010(L<jats:sup>3<\/jats:sup>)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>8<\/jats:sub>] (<jats:bold>1<\/jats:bold>), {[Cd(L)(L<jats:sup>2<\/jats:sup>)](H<jats:sub>2<\/jats:sub>O)<jats:sub>1\/2<\/jats:sub>}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> (<jats:bold>2<\/jats:bold>), and {[Cd(L<jats:sup>3<\/jats:sup>)<jats:sub>2<\/jats:sub>](H<jats:sub>2<\/jats:sub>O)<jats:sub>3\/2<\/jats:sub>(EtOH)}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> (<jats:bold>3<\/jats:bold>), in which L, L<jats:sup>2<\/jats:sup>, and L<jats:sup>3<\/jats:sup> are three urocanate tautomers. Complex <jats:bold>1<\/jats:bold> consists of two separate mononuclear units with different urocanate tautomers, which self\u2010assemble into a 3D hydrogen\u2010bonding network constructed by alternating 2D layers, whereas complexes <jats:bold>2<\/jats:bold> and <jats:bold>3<\/jats:bold> self\u2010assemble into 3D alpha\u2010polonium and four\u2010fold interpenetrated diamondoid networks, respectively. The tautomerism of the urocanate ligands and the enormous structural diversity of their complexes are present in this system, which illustrates that the reaction temperature, pressure, and the metal ions themselves act cooperatively to tune the tautomerism of the ligands and the frameworks of their metal coordination compounds. The fluorescence\u2010emission and nitrogen\u2010adsorption properties of these complexes are also investigated.<\/jats:p>","DOI":"10.1002\/asia.200600113","type":"journal-article","created":{"date-parts":[[2006,9,8]],"date-time":"2006-09-08T14:18:41Z","timestamp":1157725121000},"page":"536-543","source":"Crossref","is-referenced-by-count":19,"title":["Tuning the Formation of Cadmium(II) Urocanate Frameworks by Control of Reaction Conditions: Crystal Structure, Properties, and Theoretical Investigation"],"prefix":"10.1002","volume":"1","author":[{"given":"Ru\u2010Qiang","family":"Zou","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui\u2010Qin","family":"Zhong","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ling","family":"Jiang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yusuke","family":"Yamada","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nobuhiro","family":"Kuriyama","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiang","family":"Xu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2006,10,11]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1067208"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1083440"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja051168t"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200462787"},{"key":"e_1_2_6_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462787"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2005.07.009"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature03852"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19980605)110:11<1558::AID-ANGE1558>3.0.CO;2-7"},{"key":"e_1_2_6_8_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO;2-Z"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0392871"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200390124"},{"key":"e_1_2_6_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200390156"},{"key":"e_1_2_6_11_2","first-page":"3868","volume":"42","author":"Fan J.","year":"2003","journal-title":"Inorg. Chem."},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200453923"},{"key":"e_1_2_6_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200453923"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/B315483A"},{"key":"e_1_2_6_14_2","unstructured":"\u00a0"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar040166v"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/b501071c"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/b400879k"},{"key":"e_1_2_6_18_2","unstructured":"\u00a0"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar0401707"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200353463"},{"key":"e_1_2_6_20_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200353463"},{"key":"e_1_2_6_21_2","unstructured":"\u00a0"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19990215)111:4<557::AID-ANGE557>3.0.CO;2-Z"},{"key":"e_1_2_6_22_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19990215)38:4<536::AID-ANIE536>3.0.CO;2-3"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200305526"},{"key":"e_1_2_6_24_2","unstructured":"\u00a0"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9900432"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/b312876h"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/cg0499717"},{"key":"e_1_2_6_28_2","first-page":"2268","author":"Galet A.","year":"2005","journal-title":"Chem. Commun."},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1039\/B408961H"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200351368"},{"key":"e_1_2_6_30_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200351368"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200462214"},{"key":"e_1_2_6_31_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462214"},{"key":"e_1_2_6_32_2","unstructured":"\u00a0"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar040163i"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200500587"},{"key":"e_1_2_6_34_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200500587"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar0001012"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1039\/B406126H"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1039\/B416095A"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1039\/B409459J"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200461214"},{"key":"e_1_2_6_39_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200461214"},{"key":"e_1_2_6_40_2","unstructured":"Bruker AXS SAINT Software Reference Manual Madison WI 1998."},{"key":"e_1_2_6_41_2","unstructured":"G.\u2005M. Sheldrick SHELXTL NT Version\u20055.1 Program for Solution and Refinement of Crystal Structures University of G\u00f6ttingen G\u00f6ttingen (Germany) 1997."},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00100a030"},{"key":"e_1_2_6_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic026150n"},{"key":"e_1_2_6_44_2","doi-asserted-by":"publisher","DOI":"10.1039\/b208683b"},{"key":"e_1_2_6_45_2","doi-asserted-by":"publisher","DOI":"10.1039\/B409722J"},{"key":"e_1_2_6_46_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2005.05.029"},{"key":"e_1_2_6_47_2","doi-asserted-by":"publisher","DOI":"10.1039\/b102210p"},{"key":"e_1_2_6_48_2","doi-asserted-by":"publisher","DOI":"10.1039\/b008259g"},{"key":"e_1_2_6_49_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200460758"},{"key":"e_1_2_6_49_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200460758"},{"key":"e_1_2_6_50_2","unstructured":"\u00a0"},{"key":"e_1_2_6_51_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-72666-8"},{"key":"e_1_2_6_52_2","volume-title":"Molecular Fluorescence: Principles and Application","author":"Valeur B.","year":"2002"},{"key":"e_1_2_6_53_2","unstructured":"Implemented as the PLATON procedure: A.\u2005L. Spek A Multipurpose Crystallographic Tool Utrecht University Utrecht (The Netherlands) 1998."},{"key":"e_1_2_6_54_2","unstructured":"M.\u2005J. Frisch G.\u2005W. Trucks H.\u2005B. Schlegel G.\u2005E. Scuseria M.\u2005A. Robb J.\u2005R. Cheeseman J.\u2005A. Montgomery \u2005Jr. T. Vreven K.\u2005N. Kudin J.\u2005C. Burant J.\u2005M. Millam S.\u2005S. Iyengar J. Tomasi V. Barone B. Mennucci M. Cossi G. Scalmani N. Rega G.\u2005A. Petersson H. Nakatsuji M. Hada M. Ehara K. Toyota R. Fukuda J. Hasegawa M. Ishida T. Nakajima Y. Honda O. Kitao H. Nakai M. Klene X. Li J.\u2005E. Knox H.\u2005P. Hratchian J.\u2005B. Cross C. Adamo J. Jaramillo R. Gomperts R.\u2005E. Stratmann O. Yazyev A.\u2005J. Austin R. Cammi C. Pomelli J.\u2005W. Ochterski P.\u2005Y. Ayala K. Morokuma G.\u2005A. Voth P. Salvador J.\u2005J. Dannenberg V.\u2005G. Zakrzewski S. Dapprich A.\u2005D. Daniels M.\u2005C. Strain O. Farkas D.\u2005K. Malick A.\u2005D. Rabuck K. Raghavachari J.\u2005B. Foresman J.\u2005V. Ortiz Q. Cui A.\u2005G. Baboul S. Clifford J. Cioslowski B.\u2005B. Stefanov G. Liu A. Liashenko P. Piskorz I. Komaromi R.\u2005L. Martin D.\u2005J. Fox T. Keith M.\u2005A. Al\u2010Laham C.\u2005Y. Peng A. Nanayakkara M. Challacombe P.\u2005M.\u2005W. Gill B. Johnson W. Chen M.\u2005W. Wong C. Gonzalez J.\u2005A. Pople Gaussian\u200503 (Revision B.04) Gaussian Inc. Pittsburgh (USA) 2003."},{"key":"e_1_2_6_55_2","unstructured":"\u00a0"},{"key":"e_1_2_6_56_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.37.785"},{"key":"e_1_2_6_57_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.464913"},{"key":"e_1_2_6_58_2","unstructured":"\u00a0"},{"key":"e_1_2_6_59_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.438980"},{"key":"e_1_2_6_60_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.438955"},{"key":"e_1_2_6_61_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.447079"},{"key":"e_1_2_6_62_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.448975"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fasia.200600113","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.200600113","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T13:10:29Z","timestamp":1759929029000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.200600113"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2006,10,11]]},"references-count":73,"journal-issue":{"issue":"4","published-print":{"date-parts":[[2006,10,20]]}},"alternative-id":["10.1002\/asia.200600113"],"URL":"https:\/\/doi.org\/10.1002\/asia.200600113","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2006,10,11]]}}}