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Cyclododecane and cyclohexane were treated with <jats:italic>t<\/jats:italic>BuONO followed by triethylamine and then cyanuric chloride in a one\u2010pot manner to give laurolactam and \u03b5\u2010caprolactam, respectively, in good yields. The Beckmann rearrangement of oximes by cyanuric chloride was found to be accelerated by the use of 1,1,1,3,3,3\u2010hexafluoro\u20102\u2010propanol as solvent. The method provides the first successful environmentally benign direct synthetic route to lactams from cycloalkanes without the formation of any salt.<\/jats:p>","DOI":"10.1002\/asia.200600187","type":"journal-article","created":{"date-parts":[[2006,10,20]],"date-time":"2006-10-20T06:02:23Z","timestamp":1161324143000},"page":"712-716","source":"Crossref","is-referenced-by-count":17,"title":["One\u2010Pot Synthesis of Lactams from Cycloalkanes and <i>tert<\/i>\u2010Butyl Nitrite by Using <i>N<\/i>\u2010Hydroxyphthalimide as Key Catalyst"],"prefix":"10.1002","volume":"1","author":[{"given":"Masaharu","family":"Hashimoto","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Satoshi","family":"Sakaguchi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yasutaka","family":"Ishii","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2006,11,9]]},"reference":[{"key":"e_1_2_6_1_2","first-page":"72","volume-title":"Encyclopedia of Chemical Processing and Design","author":"Luedeke V. 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