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Interestingly, one of the major products in these reactions was the result of the recombination of anilino and alkyl radicals to form the corresponding hemiaminal compounds. The structure of the recombination products was assigned unambiguously after proton\/deuterium exchange experiments followed by MS and MS\/MS analysis.<\/jats:p>","DOI":"10.1002\/asia.200700211","type":"journal-article","created":{"date-parts":[[2007,11,26]],"date-time":"2007-11-26T11:53:13Z","timestamp":1196077993000},"page":"102-112","source":"Crossref","is-referenced-by-count":12,"title":["Determination of Solvent\u2010Trapped Products Obtained by Photolysis of Aryl Azides in 2,2,2\u2010Trifluoroethanol"],"prefix":"10.1002","volume":"3","author":[{"given":"Magne\u2005O.","family":"Sydnes","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Issei","family":"Doi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ayako","family":"Ohishi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Masaki","family":"Kuse","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Minoru","family":"Isobe","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2007,12,19]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1038\/224511a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/mas.20082"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19951071204"},{"key":"e_1_2_6_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199512961"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/0040-4020(95)00598-3"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja980978k"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/bc00031a014"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.73.465"},{"key":"e_1_2_6_8_2","unstructured":"\u00a0"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja061520i"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/bi0516632"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00039a016"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00294a015"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar00060a004"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr040055"},{"key":"e_1_2_6_15_2","first-page":"510","volume-title":"Reactive Intermediates Chemistry","author":"Platz M. 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CH3CN\/H2O 1:1 containing 0.1\u2009% TFA 0.5\u2005mL\u2009min\u22121 254\u2005nm). Concentration of the fraction withtr=12.6\u2005min gave hemiaminal47."},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja015953r"},{"key":"e_1_2_6_39_2","unstructured":"Develosil C30\u2010UG\u20105 (4.6\u00d7250\u2005mm i.\u2009d.) CH3CN\/H2O 1:1 containing 0.1\u2009% TFA 0.5\u2005mL\u2009min\u22121 254\u2005nm or 295\u2005nm."},{"key":"e_1_2_6_40_2","unstructured":"The UV absorbance for the primary product at 254\u2005nm is much lower than the absorbance at this wavelength for the starting material and the other products that are formed (see UV spectra depicted in Figure\u20054 for specific examples). 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