{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T00:45:33Z","timestamp":1789951533427,"version":"4.0.1"},"reference-count":28,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2011,4,15]],"date-time":"2011-04-15T00:00:00Z","timestamp":1302825600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2011,7,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Ultra\u2010high\u2010pressure hydrogen\u2010storage performance (up to 1900\u2005bar) was investigated for mesoporous chromium terephthalate MIL\u2010101 and its inclusion compounds containing ionic clusters [Re<jats:sub>4<\/jats:sub>S<jats:sub>4<\/jats:sub>F<jats:sub>12<\/jats:sub>]<jats:sup>4\u2212<\/jats:sup> and [SiW<jats:sub>11<\/jats:sub>O<jats:sub>39<\/jats:sub>]<jats:sup>7\u2212<\/jats:sup> within the porous framework. The maximum specific hydrogen uptake values (total) for MIL\u2010101 are 12.3 (at 81) and 7.2\u2005wt.\u2009% (at 293\u2005K). Such unique measurement conditions allowed us to identify the density of the absorbed hydrogen directly from the excess sorption isotherm curves. The corresponding density values were found to be almost comparable at low temperature, but significantly different at ambient temperature, which indicated an increase of more than double in the number of hydrogen binding sites in the case of the inclusion compounds with rhenium clusters.<\/jats:p>","DOI":"10.1002\/asia.201000871","type":"journal-article","created":{"date-parts":[[2011,4,15]],"date-time":"2011-04-15T13:06:46Z","timestamp":1302872806000},"page":"1854-1859","source":"Crossref","is-referenced-by-count":24,"title":["Influence of MIL\u2010101 Doping by Ionic Clusters on Hydrogen Storage Performance up to 1900 Bar"],"prefix":"10.1002","volume":"6","author":[{"given":"Semen N.","family":"Klyamkin","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Elena A.","family":"Berdonosova","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ekaterina V.","family":"Kogan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Konstantin A.","family":"Kovalenko","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Danil N.","family":"Dybtsev","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vladimir P.","family":"Fedin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2011,4,15]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1038\/35104634"},{"key":"e_1_2_6_2_2","unstructured":"Various reports including recent progress developments toward hydrogen economy are available on the US Department of Energy (DOE) websitewww.hydrogen.energy.gov."},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/B802882F"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/b802256a"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/b802430h"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/B712576N"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200462787"},{"key":"e_1_2_6_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462787"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1192160"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200802087"},{"key":"e_1_2_6_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200802087"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/aic.11362"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic800700h"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1007\/s11172-009-0223-z"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/la100601a"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1116275"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/b703608f"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/la800227x"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2008.05.014"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic902459f"},{"key":"e_1_2_6_19_2","unstructured":"The hydrogen sorption measurements were carried out in a liquid nitrogen bath the temperature of which was measured directly. The observed temperature is slightly above the boiling point of nitrogen (77\u2005K) owing to the impurities (such as O2 Ar) which are continuously accumulating in the liquid nitrogen when the Dewar vessel is exposed to the atmosphere."},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/0925-8388(93)90642-Z"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr60253a002"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200600105"},{"key":"e_1_2_6_22_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200600105"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja058213h"},{"key":"e_1_2_6_24_2","unstructured":"Here we assume that the excess hydrogen uptake is exclusively attributed to the adsorbed H2molecules as a monolayer interacting with the surface. The following parameters were taken into account:r(H2)=2.4\u2005\u00c5; MIL\u2010101 density=0.58\u2005g\u2009cm\u22123;Sa=3800\u2005m2\u2009g\u22121(see Table\u20051). The MIL\u2010101 unit cell has a volume of 720\u22c5103\u2005\u00c53and contains 272 formula units [Cr3O(C8H4O4)3(H2O)2F]."},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1088\/0022-3719\/19\/19\/013"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fasia.201000871","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.201000871","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T19:38:28Z","timestamp":1759952308000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.201000871"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2011,4,15]]},"references-count":28,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2011,7,4]]}},"alternative-id":["10.1002\/asia.201000871"],"URL":"https:\/\/doi.org\/10.1002\/asia.201000871","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2011,4,15]]}}}