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Two geometric isomers of <jats:bold>6<\/jats:bold> (<jats:bold>6a<\/jats:bold> and <jats:bold>6\u2009b<\/jats:bold>) have been isolated. The structures of these products, which have been elucidated by single\u2010crystal X\u2010ray crystallography, show two structural types, I and II, depending on the relative dispositions of the ligands. Type\u2005I structures contain a carbenic carbon atom <jats:italic>trans<\/jats:italic> to the oxygen atom, whereas two phosphorus atoms are <jats:italic>trans<\/jats:italic> to bromine and oxygen atoms. The type\u2005II system comprises a carbene carbon atom <jats:italic>trans<\/jats:italic> to one of the phosphorus atoms, whereas the other phosphorus is <jats:italic>trans<\/jats:italic> to the oxygen atom, with the bromine <jats:italic>trans<\/jats:italic> to the remaining oxygen atom. Complexes <jats:bold>2<\/jats:bold>, <jats:bold>3<\/jats:bold>, <jats:bold>4<\/jats:bold>, and <jats:bold>6a<\/jats:bold> belong to type\u2005I, whereas <jats:bold>5<\/jats:bold> and <jats:bold>6\u2009b<\/jats:bold> are of type\u2005II. The kinetic product <jats:bold>6\u2009b<\/jats:bold> eventually converts into <jats:bold>6a<\/jats:bold> upon standing. These complexes are active towards catalytic reduction of <jats:italic>para<\/jats:italic>\u2010methyl acetophenone by 2\u2010propanol at 82\u2009\u00b0C under 1\u2009% catalyst load giving the corresponding alcohols. The dppm complex <jats:bold>2<\/jats:bold> shows the good yields (91\u201397\u2009%) towards selected ketones.<\/jats:p>","DOI":"10.1002\/asia.201000930","type":"journal-article","created":{"date-parts":[[2011,4,15]],"date-time":"2011-04-15T13:07:22Z","timestamp":1302872842000},"page":"1485-1491","source":"Crossref","is-referenced-by-count":10,"title":["Syntheses and Structures of Ruthenium(II) N,S\u2010Heterocyclic Carbene Diphosphine Complexes and their Catalytic Activity towards Transfer Hydrogenation"],"prefix":"10.1002","volume":"6","author":[{"given":"Nini","family":"Ding","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"T. S. 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