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The association of a significant amount of water molecules in DNA\u2010based materials for the intactness of the DNA structure and their dynamic role in the charge\u2010transfer (CT) dynamics is less documented in contemporary literature. In the present study, we have used a genomic DNA\u2013cetyltrimethyl ammonium chloride (CTMA) complex, a technological important biomaterial, and Hoechest 33258 (H258), a well\u2010known DNA minor groove binder, as fluorogenic probe for the dynamic solvation studies. The CT dynamics of CdSe\/ZnS quantum dots (QDs; 5.2\u2005nm) embedded in the as\u2010prepared and swollen biomaterial have also been studied and correlated with that of the timescale of solvation. We have extended our studies on the temperature\u2010dependent CT dynamics of QDs in a nanoenvironment of an anionic, sodium bis(2\u2010ethylhexyl)sulfosuccinate reverse micelle (AOT RMs), whereby the number of water molecules and their dynamics can be tuned in a controlled manner. A direct correlation of the dynamics of solvation and that of the CT in the nanoenvironments clearly suggests that the hydration barrier within the Arrhenius framework essentially dictates the charge\u2010transfer dynamics.<\/jats:p>","DOI":"10.1002\/asia.201400062","type":"journal-article","created":{"date-parts":[[2014,3,24]],"date-time":"2014-03-24T22:17:30Z","timestamp":1395699450000},"page":"1395-1402","source":"Crossref","is-referenced-by-count":20,"title":["Ultrafast Dynamics of Solvation and Charge Transfer in a DNA\u2010Based Biomaterial"],"prefix":"10.1002","volume":"9","author":[{"given":"Susobhan","family":"Choudhury","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Subrata","family":"Batabyal","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tanumoy","family":"Mondol","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dilip","family":"Sao","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peter","family":"Lemmens","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Samir Kumar","family":"Pal","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2014,3,24]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature01406"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/B808030E"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp806791s"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/nphoton.2006.56"},{"key":"e_1_2_6_5_2","first-page":"73","volume-title":"Org. 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