{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,22]],"date-time":"2025-10-22T03:01:54Z","timestamp":1761102114356,"version":"build-2065373602"},"reference-count":79,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2014,11,21]],"date-time":"2014-11-21T00:00:00Z","timestamp":1416528000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2015,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Fluoride\u2010catalyzed nucleophilic addition of a difluoro(phenylsulfanyl)methyl group (\u201cPhSCF<jats:sub>2<\/jats:sub>\u201d) generated from PhSCF<jats:sub>2<\/jats:sub>SiMe<jats:sub>3<\/jats:sub> to nitrones was accomplished in satisfactory yields. High diastereoselectivities were observed with chiral polyoxygenated cyclic nitrones to provide the corresponding adducts, which were further manipulated to afford <jats:italic>gem<\/jats:italic>\u2010difluoromethylenated polyhydroxypyrrolizidines and \u2010indolizidines.<\/jats:p>","DOI":"10.1002\/asia.201403023","type":"journal-article","created":{"date-parts":[[2014,11,21]],"date-time":"2014-11-21T16:08:02Z","timestamp":1416586082000},"page":"948-968","source":"Crossref","is-referenced-by-count":18,"title":["Stereoselective Nucleophilic Addition of PhSCF<sub>2<\/sub>SiMe<sub>3<\/sub> to Chiral Cyclic Nitrones: Asymmetric Synthesis of <i>gem<\/i>\u2010Difluoromethylenated Polyhydroxypyrrolizidines and \u2010indolizidines"],"prefix":"10.1002","volume":"10","author":[{"given":"Korkit","family":"Korvorapun","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Darunee","family":"Soorukram","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chutima","family":"Kuhakarn","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Patoomratana","family":"Tuchinda","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Vichai","family":"Reutrakul","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Manat","family":"Pohmakotr","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2014,11,21]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"For reviews see:"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470281895"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1131943"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470988589"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/bk-2005-0911"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/352760393X"},{"volume-title":"Selective Fluorination in Organic and Bioorganic Chemistry, Vol.\u2005110","year":"1991","key":"e_1_2_6_7_2"},{"key":"e_1_2_6_8_2","unstructured":"For reviews see:"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200704700"},{"key":"e_1_2_6_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200704700"},{"key":"e_1_2_6_10_2","doi-asserted-by":"crossref","first-page":"921","DOI":"10.1021\/ar700149s","volume":"40","author":"Surya Prakash G. K.","year":"2007","journal-title":"Acc. Chem. Res."},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200460441"},{"key":"e_1_2_6_11_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200460441"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr030143e"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-662-04164-2"},{"key":"e_1_2_6_14_2","unstructured":"For selected recent references see:"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jfluchem.2010.03.003"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/9781444312096"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/B711844A"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/B610213C"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/jm800219f"},{"key":"e_1_2_6_20_2","unstructured":"See for some recent examples:"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo4024705"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol500803r"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol5002939"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol5001395"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja4114825"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201304473"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201309535"},{"key":"e_1_2_6_27_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201309535"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC03321C"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3CC48468H"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja409941r"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201306703"},{"key":"e_1_2_6_31_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201306703"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201304395"},{"key":"e_1_2_6_32_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201304395"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201300763"},{"key":"e_1_2_6_33_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201300763"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc39066g"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol202208b"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol802361p"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol801443s"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo800768q"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo800337t"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo800721w"},{"key":"e_1_2_6_41_2","first-page":"1989","author":"Hang X.\u2010C.","year":"2008","journal-title":"Synlett"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo702328v"},{"key":"e_1_2_6_43_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2008.10.006"},{"key":"e_1_2_6_44_2","unstructured":"\u00a0"},{"key":"e_1_2_6_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201310747"},{"key":"e_1_2_6_45_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201310747"},{"key":"e_1_2_6_46_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3ob27193e"},{"key":"e_1_2_6_47_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201300998"},{"key":"e_1_2_6_48_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo802794u"},{"key":"e_1_2_6_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo301327s"},{"key":"e_1_2_6_50_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201201599"},{"key":"e_1_2_6_51_2","unstructured":"See for some recent examples:"},{"key":"e_1_2_6_52_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201301671"},{"key":"e_1_2_6_53_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol400566j"},{"key":"e_1_2_6_54_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0031-9422(00)00451-9"},{"key":"e_1_2_6_55_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2010.01.011"},{"key":"e_1_2_6_56_2","unstructured":"\u00a0"},{"key":"e_1_2_6_57_2","first-page":"488","author":"Wang W.\u2010B.","year":"2010","journal-title":"Synlett"},{"key":"e_1_2_6_58_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo048237r"},{"key":"e_1_2_6_59_2","first-page":"1473","author":"Bandaru A.","year":"2012","journal-title":"Synlett"},{"key":"e_1_2_6_60_2","unstructured":"For examples of stereoselective addition of RMgX to cyclic nitrones see:"},{"key":"e_1_2_6_61_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200800098"},{"key":"e_1_2_6_62_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmc.2008.10.063"},{"key":"e_1_2_6_63_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-2007-991059"},{"key":"e_1_2_6_64_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2006.07.120"},{"key":"e_1_2_6_65_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol0609210"},{"key":"e_1_2_6_66_2","first-page":"35","author":"Toyao A.","year":"2003","journal-title":"Synlett"},{"key":"e_1_2_6_67_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol047356q"},{"key":"e_1_2_6_68_2","unstructured":"\u00a0"},{"key":"e_1_2_6_69_2","doi-asserted-by":"publisher","DOI":"10.1093\/oso\/9780198502418.001.0001"},{"key":"e_1_2_6_70_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527618293"},{"volume-title":"Stereochemistry of Radical Reactions: Concepts, Guidelines, and Synthetic Applications","year":"1996","author":"Curran D. P.","key":"e_1_2_6_71_2"},{"volume-title":"Free Radical Chain Reactions in Organic Synthesis","year":"1991","author":"Motherwell W. B.","key":"e_1_2_6_72_2"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fasia.201403023","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.201403023","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T19:18:01Z","timestamp":1759951081000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.201403023"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,11,21]]},"references-count":79,"journal-issue":{"issue":"4","published-print":{"date-parts":[[2015,4]]}},"alternative-id":["10.1002\/asia.201403023"],"URL":"https:\/\/doi.org\/10.1002\/asia.201403023","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"type":"print","value":"1861-4728"},{"type":"electronic","value":"1861-471X"}],"subject":[],"published":{"date-parts":[[2014,11,21]]}}}