{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T10:57:13Z","timestamp":1791284233051,"version":"4.1.0"},"reference-count":66,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2015,2,18]],"date-time":"2015-02-18T00:00:00Z","timestamp":1424217600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2015,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    A number of three\u2010fold\n                    <jats:italic>C<\/jats:italic>\n                    <jats:sub>\n                      3\n                      <jats:italic>v<\/jats:italic>\n                    <\/jats:sub>\n                    \u2010symmetrical tribenzotriquinacene (TBTQ) cavitands were synthesized by a \u201cmetamorphosis\u2010to\u2010half\u201d strategy, employing six\u2010fold etherification reactions between the hexakis(chloromethyl)\u2010TBTQ intermediate\n                    <jats:bold>2\u2009a<\/jats:bold>\n                    and various 5\u2010functionalized resorcinols. X\u2010ray structure analyses of single crystals of the cavitands revealed limited rotational flexibility of the resorcinol bridging units, which enables an apical, nearly co\u2010axial orientation of the three functional groups and, as a consequence, the construction of nanoscale cage\u2010like molecules via covalent or coordination bonding. On this basis, two TBTQ\u2010based hemicryptophanes were prepared from the TBTQ cavitands via covalent bond formation in good yields. A dumbbell\u2010shaped TBTQ\u2010based metallo\u2010cryptophane was also synthesized in 34\u2009% yield by a solvothermal reaction between cadmium nitrate and two equivalents of the TBTQ\u2010cavitand triacid, as confirmed by single\u2010crystal X\u2010ray diffraction and MALDI\u2010ToF mass spectrometry.\n                  <\/jats:p>","DOI":"10.1002\/asia.201403438","type":"journal-article","created":{"date-parts":[[2015,2,2]],"date-time":"2015-02-02T07:27:24Z","timestamp":1422862044000},"page":"1150-1158","source":"Crossref","is-referenced-by-count":22,"title":["Versatile Syntheses of Hemi\u2010Cryptophanes and a Metallo\u2010Cryptophane from a Hexa\u2010Functionalized\n                    <i>C<\/i>\n                    <sub>\n                      3\n                      <i>v<\/i>\n                    <\/sub>\n                    \u2010Symmetrical Tribenzotriquinacene (TBTQ) 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Mughal B. Neumann H.\u2010G. Stammler Z.\u2010M. Li J. Wei X.\u2010P. Cao D. Kuck Eur. J. Org. Chem.2015 accepted for publication;"},{"key":"e_1_2_6_56_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201303031"},{"key":"e_1_2_6_57_2","unstructured":"CCDC\u20051020941 (9) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre viawww.ccdc.cam.ac.uk\/data_request\/cif. The alert level A and level B of data are ascribed to the disorder of the crystal and the disorder could not be eliminated even when the data were collected at lower temperature. 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