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Four selenidostannates, namely, 2D\u2010(Bmmim)<jats:sub>3<\/jats:sub>[Ni(en)<jats:sub>3<\/jats:sub>]<jats:sub>2<\/jats:sub>[Sn<jats:sub>9<\/jats:sub>Se<jats:sub>21<\/jats:sub>]Cl (<jats:bold>1<\/jats:bold>, en=ethylenediamine), 2D\u2010(Bmmim)<jats:sub>8<\/jats:sub>[Ni<jats:sub>2<\/jats:sub>(teta)<jats:sub>2<\/jats:sub>(\u03bc\u2010teta)]Sn<jats:sub>18<\/jats:sub>Se<jats:sub>42<\/jats:sub> (<jats:bold>2<\/jats:bold>, teta=triethylenetetramine), 2D\u2010(Bmmim)<jats:sub>4<\/jats:sub>[Ni(tepa)Cl]<jats:sub>2<\/jats:sub>[Ni(tepa)Sn<jats:sub>12<\/jats:sub>Se<jats:sub>28<\/jats:sub>] (<jats:bold>3<\/jats:bold>, tepa=tetraethylenepentamine), and 3D\u2010(Bmmim)<jats:sub>2<\/jats:sub>[Ni(1,2\u2010pda)<jats:sub>3<\/jats:sub>]Sn<jats:sub>8<\/jats:sub>Se<jats:sub>18<\/jats:sub> (<jats:bold>4<\/jats:bold>, 1,2\u2010pda=1,2\u2010diaminopropane), were obtained. Single\u2010crystal X\u2010ray diffraction analyses revealed that compounds <jats:bold>1<\/jats:bold> and <jats:bold>2<\/jats:bold> possess a lamellar anionic [Sn<jats:sub>3<\/jats:sub>Se<jats:sub>7<\/jats:sub>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub><jats:sup>2<jats:italic>n<\/jats:italic>\u2212<\/jats:sup> structure comprising distinct eight\u2010membered ring units, whereas <jats:bold>3<\/jats:bold> features a MAC\u2010decorated anionic [Ni(tepa)Sn<jats:sub>12<\/jats:sub>Se<jats:sub>28<\/jats:sub>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub><jats:sup>6<jats:italic>n<\/jats:italic>\u2212<\/jats:sup> layered structure. In contrast to <jats:bold>1<\/jats:bold>\u2013<jats:bold>3<\/jats:bold>, compound <jats:bold>4<\/jats:bold> exhibits a 3D open framework of anionic [Sn<jats:sub>4<\/jats:sub>Se<jats:sub>9<\/jats:sub>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub><jats:sup>2<jats:italic>n<\/jats:italic>\u2212<\/jats:sup>. The structural variation from <jats:bold>1<\/jats:bold> to <jats:bold>4<\/jats:bold> clearly indicates that on the basis of the synergistic structure\u2010directing ability of the MACs and ILs, variation of the organic polyamine ligand has a significant impact on the formation of selenidostannates.<\/jats:p>","DOI":"10.1002\/asia.201600073","type":"journal-article","created":{"date-parts":[[2016,4,2]],"date-time":"2016-04-02T19:11:44Z","timestamp":1459624304000},"page":"1555-1564","source":"Crossref","is-referenced-by-count":25,"title":["Synthesizing 2D and 3D Selenidostannates in Ionic Liquids: The Synergistic Structure\u2010Directing Effects of Ionic Liquids and Metal\u2013Amine Complexes"],"prefix":"10.1002","volume":"11","author":[{"given":"Cheng\u2010Feng","family":"Du","sequence":"first","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 P.R. China"},{"name":"University of Chinese Academy of Sciences, Beijing  100049 P.R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nan\u2010Nan","family":"Shen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 P.R. China"},{"name":"University of Chinese Academy of Sciences, Beijing  100049 P.R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jian\u2010Rong","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 P.R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Min\u2010Ting","family":"Hao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 P.R. China"},{"name":"College of Materials Science and Engineering Fujian Normal University  Fuzhou Fujian 350002 P.R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zi","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Chemistry Fuzhou University  Fuzhou Fujian 350002 P.R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiao\u2010Ying","family":"Huang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 P.R. 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