{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T03:19:52Z","timestamp":1791343192675,"version":"4.3.1"},"reference-count":51,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2016,3,30]],"date-time":"2016-03-30T00:00:00Z","timestamp":1459296000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"Shanghai Pujiang Talent Program","award":["11J1402500"],"award-info":[{"award-number":["11J1402500"]}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["21171056"],"award-info":[{"award-number":["21171056"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2016,5,6]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>We have developed I<jats:sub>2<\/jats:sub>\u2010 or <jats:italic>N<\/jats:italic>\u2010iodosuccinimide (NIS)\u2010mediated amidiniumation of <jats:italic>N<\/jats:italic>\u2010alkenyl formamidines for the syntheses of cyclic formamidinium salts, some of which could be directly used as N\u2010heterocyclic carbene (NHC) precursors. Treatment of iodine\u2010containing formamidinium salts with Al<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> led to the formation of cyclic formamidinium salts with an unsaturated backbone. A rhodium(I) complex ligated by a representative NHC was prepared by the reaction of [Rh(cod)Cl]<jats:sub>2<\/jats:sub> (cod=1,5\u2010cyclooctadiene) with the free carbene obtained in situ from deprotonation of the corresponding formamidinium salts. The NHCs prepared in situ can also react with S<jats:sub>8<\/jats:sub> to afford the corresponding thiones.<\/jats:p>","DOI":"10.1002\/asia.201600182","type":"journal-article","created":{"date-parts":[[2016,3,9]],"date-time":"2016-03-09T04:01:38Z","timestamp":1457496098000},"page":"1361-1365","source":"Crossref","is-referenced-by-count":12,"title":["Facile Syntheses of N\u2010Heterocyclic Carbene Precursors through I<sub>2<\/sub>\u2010 or NIS\u2010Promoted Amidiniumation of <i>N<\/i>\u2010Alkenyl Formamidines"],"prefix":"10.1002","volume":"11","author":[{"given":"Jing","family":"Li","sequence":"first","affiliation":[{"name":"Key Laboratory for Advanced Materials and Institute of Fine Chemicals School of Chemistry&amp;Molecular Engineering East China University of Science and Technology  130\u2005Mei Long Road Shanghai 200237 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiajun","family":"Jiao","sequence":"additional","affiliation":[{"name":"Key Laboratory for Advanced Materials and Institute of Fine Chemicals School of Chemistry&amp;Molecular Engineering East China University of Science and Technology  130\u2005Mei Long Road Shanghai 200237 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Caiyun","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory for Advanced Materials and Institute of Fine Chemicals School of Chemistry&amp;Molecular Engineering East China University of Science and Technology  130\u2005Mei Long Road Shanghai 200237 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Min","family":"Shi","sequence":"additional","affiliation":[{"name":"Key Laboratory for Advanced Materials and Institute of Fine Chemicals School of Chemistry&amp;Molecular Engineering East China University of Science and Technology  130\u2005Mei Long Road Shanghai 200237 China"},{"name":"State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences  354\u2005Fenglin Road Shanghai 200032 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory for Advanced Materials and Institute of Fine Chemicals School of Chemistry&amp;Molecular Engineering East China University of Science and Technology  130\u2005Mei Long Road Shanghai 200237 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2016,3,30]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"For selected reviews see:"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9002424"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr800524f"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900074m"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr8005203"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr8005153"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr050004s"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr068372z"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201001865"},{"key":"e_1_2_2_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201001865"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar980126p"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201000472"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201401131"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201200217"},{"key":"e_1_2_2_14_1","unstructured":"\u00a0"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs60146c"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100328e"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703883"},{"key":"e_1_2_2_17_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200703883"},{"key":"e_1_2_2_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc15609h"},{"key":"e_1_2_2_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc34952c"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc45823g"},{"key":"e_1_2_2_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc35020c"},{"key":"e_1_2_2_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201201082"},{"key":"e_1_2_2_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201508221"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201508221"},{"key":"e_1_2_2_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200605083"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200605083"},{"key":"e_1_2_2_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC07082H"},{"key":"e_1_2_2_26_1","unstructured":"\u00a0"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/cs400138b"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2010.03.082"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol302855z"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0690(200209)2002:18<3171::AID-EJOC3171>3.0.CO;2-L"},{"key":"e_1_2_2_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201102453"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3sc50410g"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1039\/c4ra00383g"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol4003866"},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc44711a"},{"key":"e_1_2_2_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar900059r"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(98)00827-8"},{"key":"e_1_2_2_38_2","doi-asserted-by":"publisher","DOI":"10.1002\/asia.200700373"},{"key":"e_1_2_2_39_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2sc20242e"},{"key":"e_1_2_2_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja981419g"},{"key":"e_1_2_2_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc05105e"},{"key":"e_1_2_2_42_1","unstructured":"\u00a0"},{"key":"e_1_2_2_43_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0960-894X(99)00203-6"},{"key":"e_1_2_2_44_2","doi-asserted-by":"publisher","DOI":"10.1021\/jm980118e"},{"key":"e_1_2_2_44_3","doi-asserted-by":"publisher","DOI":"10.1016\/S0223-5234(98)80033-0"},{"key":"e_1_2_2_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc01058h"},{"key":"e_1_2_2_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo000744v"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fasia.201600182","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fasia.201600182","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.201600182","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T19:18:30Z","timestamp":1759951110000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.201600182"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,3,30]]},"references-count":51,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2016,5,6]]}},"alternative-id":["10.1002\/asia.201600182"],"URL":"https:\/\/doi.org\/10.1002\/asia.201600182","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2016,3,30]]}}}