{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T14:44:48Z","timestamp":1791297888927,"version":"4.1.0"},"reference-count":31,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2017,1,18]],"date-time":"2017-01-18T00:00:00Z","timestamp":1484697600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2017,2,16]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A method that allows hindered <jats:italic>ortho<\/jats:italic>\u2010substituted aryl iodides to be efficiently coupled to phenylboronic acid using a gold\u2010catalyzed C\u2212C bond formation is presented. The use of a molecularly\u2010defined dinuclear gold chloride catalytic precursor that is stabilized by a new tetradentate (<jats:italic>N<\/jats:italic>,<jats:italic>N\u2032<\/jats:italic>)\u2010diamino\u2010(<jats:italic>P,P\u2032<\/jats:italic>)\u2010diphosphino ferrocene hybrid ligand in a Suzuki\u2010type reaction is described for the first time. Electron\u2010rich isopropyl groups on phosphorus were found essential for a superior activity, while the performances of a set of analogous gold dinuclear complexes that were fully characterized by multinuclear NMR spectroscopy and XRD analysis, were investigated. Therefore, arylation of <jats:italic>para<\/jats:italic> and <jats:italic>ortho<\/jats:italic>\u2010substituted iodoarenes bearing electron\u2010rich, electron\u2010poor functional groups, and even hindered polycyclic aromatic compounds is described.<\/jats:p>","DOI":"10.1002\/asia.201601583","type":"journal-article","created":{"date-parts":[[2017,1,18]],"date-time":"2017-01-18T09:38:33Z","timestamp":1484732313000},"page":"459-464","source":"Crossref","is-referenced-by-count":32,"title":["Gold\u2010Catalyzed Suzuki Coupling of <i>ortho<\/i>\u2010Substituted Hindered Aryl Substrates"],"prefix":"10.1002","volume":"12","author":[{"given":"Nejib","family":"Dwadnia","sequence":"first","affiliation":[{"name":"Universit\u00e9 de Bourgogne Institut de Chimie Mol\u00e9culaire de l'Universit\u00e9 de Bourgogne UMR-CNRS 6302\u2014Universit\u00e9 de Bourgogne Franche-Comt\u00e9 (UBFC)  9, avenue Alain Savary 21078 Dijon 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