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The trimer of interest contains a central dendrimer with a butadiyne\u2010linked zinc porphyrin dimer ((ZnP)<jats:sub>2<\/jats:sub>) core, in addition to two terminal dendrimers with zinc porphyrin (ZnP) cores. The obtained absorption spectra indicate that the unfolded form is the exclusive conformer in chloroform, while the addition of 1,4\u2010diazabicyclo[2.2.2]octane (DABCO) in chloroform leads to transformation from the unfolded to the folded structure containing two DABCO units per trimer; the folded structure originates from the cross\u2010linking of (ZnP)<jats:sub>2<\/jats:sub> and ZnP with DABCO. 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