{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T13:30:45Z","timestamp":1790775045730,"version":"4.1.0"},"reference-count":55,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2018,2,16]],"date-time":"2018-02-16T00:00:00Z","timestamp":1518739200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100004663","name":"Ministry of Science and Technology in Taiwan","doi-asserted-by":"crossref","award":["MOST 106-2113-M-259-010"],"award-info":[{"award-number":["MOST 106-2113-M-259-010"]}],"id":[{"id":"10.13039\/501100004663","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2018,3,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Atomically precise Cu\u2010rich bimetallic superatom clusters have been synthesized by adopting a galvanic exchange strategy. [Cu@Cu\n                    <jats:sub>12<\/jats:sub>\n                    (S\n                    <jats:sub>2<\/jats:sub>\n                    CN\n                    <jats:sup>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sup>\n                    Bu\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>6<\/jats:sub>\n                    (C\u2261CPh)\n                    <jats:sub>4<\/jats:sub>\n                    ][CuCl\n                    <jats:sub>2<\/jats:sub>\n                    ] (\n                    <jats:bold>1<\/jats:bold>\n                    ) was used as a template to generate compositionally uniform clusters [M@Cu\n                    <jats:sub>12<\/jats:sub>\n                    (S\n                    <jats:sub>2<\/jats:sub>\n                    CN\n                    <jats:sup>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sup>\n                    Bu\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>6<\/jats:sub>\n                    (C\u2261CPh)\n                    <jats:sub>4<\/jats:sub>\n                    ][CuCl\n                    <jats:sub>2<\/jats:sub>\n                    ], where M=Ag (\n                    <jats:bold>2<\/jats:bold>\n                    ), Au (\n                    <jats:bold>3<\/jats:bold>\n                    ). Structures of\n                    <jats:bold>1<\/jats:bold>\n                    ,\n                    <jats:bold>2<\/jats:bold>\n                    and\n                    <jats:bold>3<\/jats:bold>\n                    were determined by single crystal X\u2010ray diffraction and the results were supported by ESI\u2010MS. The anatomies of clusters\u2005\n                    <jats:bold>1<\/jats:bold>\n                    \u2013\n                    <jats:bold>3<\/jats:bold>\n                    are very similar, with a centred cuboctahedral cationic core that is surrounded by six di\u2010butyldithiocarbamate (dtc) and four phenylacetylide ligands. The doped Ag and Au atoms were found to preferentially occupy the centre of the 13\u2010atom cuboctahedral core. Experimental and theoretical analyses of the synthesized clusters revealed that both Ag and Au doping result in significant changes in cluster stability, optical characteristics and enhancement in luminescence properties.\n                  <\/jats:p>","DOI":"10.1002\/asia.201701753","type":"journal-article","created":{"date-parts":[[2018,1,24]],"date-time":"2018-01-24T02:22:46Z","timestamp":1516760566000},"page":"500-504","source":"Crossref","is-referenced-by-count":65,"title":["Synthesis of Two\u2010Electron Bimetallic Cu\u2013Ag and Cu\u2013Au Clusters by using [Cu\n                    <sub>13<\/sub>\n                    (S\n                    <sub>2<\/sub>\n                    CN\n                    <sup>\n                      <i>n<\/i>\n                    <\/sup>\n                    Bu\n                    <sub>2<\/sub>\n                    )\n                    <sub>6<\/sub>\n                    (C\u2261\n                    <i>CPh<\/i>\n                    )\n                    <sub>4<\/sub>\n                    ]\n                    <sup>+<\/sup>\n                    as a Template"],"prefix":"10.1002","volume":"13","author":[{"given":"Rhone P. Brocha","family":"Silalahi","sequence":"first","affiliation":[{"name":"Department of Chemistry National Dong Hwa University  No. 1, Sec. 2, Da Hsueh Rd., Shoufeng Hualien 97401 Taiwan R.O.C."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kiran Kumarvarma","family":"Chakrahari","sequence":"additional","affiliation":[{"name":"Department of Chemistry National Dong Hwa University  No. 1, Sec. 2, Da Hsueh Rd., Shoufeng Hualien 97401 Taiwan R.O.C."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian\u2010Hong","family":"Liao","sequence":"additional","affiliation":[{"name":"Department of Chemistry National Dong Hwa University  No. 1, Sec. 2, Da Hsueh Rd., Shoufeng Hualien 97401 Taiwan R.O.C."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Samia","family":"Kahlal","sequence":"additional","affiliation":[{"name":"Univ Rennes CNRS, ISCR\u2013UMR 6226  35000 Rennes France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu\u2010Chiao","family":"Liu","sequence":"additional","affiliation":[{"name":"Institute of Chemistry Academia Sinica  Taipei Taiwan 115 R.O.C."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ming\u2010Hsi","family":"Chiang","sequence":"additional","affiliation":[{"name":"Institute of Chemistry Academia Sinica  Taipei Taiwan 115 R.O.C."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jean\u2010Yves","family":"Saillard","sequence":"additional","affiliation":[{"name":"Univ Rennes CNRS, ISCR\u2013UMR 6226  35000 Rennes France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0801-6499","authenticated-orcid":false,"given":"C. 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Crystallographic data of2: C86H128AgCl2Cu13N6S12 Monoclinic Cc a=19.9912(5)\u2005\u00c5 b=34.0722(7)\u2005\u00c5 c=17.4502(4) \u00c5.\u03b1=90\u00b0 \u03b2=117.9405(5)\u00b0 \u03b3=90\u00b0.V=10500.6(4)\u2005\u00c53 Z=4 \u03c1 calcd=1.667\u2005cm\u22123 \u03bc=3.087\u2005mm\u22121 Goodness-of-fit on F2: 1.027 R1=0.0225 wR2=0.0545 21003 independent reflections [2\u03b8\u226450.00\u00b0] and 1093 parameters.3: C86H128AuCl2Cu13N6S12 Monoclinic Cc a=19.9711(8)\u2005\u00c5 b=34.0430(13)\u2005\u00c5 c=17.4580(7) \u00c5.\u03b1=90\u00b0 \u03b2=117.9804(7)\u00b0 \u03b3=90\u00b0.V=10481.8(7)\u2005\u00c53 Z=4 \u03c1 calcd=1.726\u2005cm\u22123 \u03bc=4.303\u2005mm\u22121 Goodness-of-fit on F2: 0.950 R1=0.0234 wR2=0.0577 20320 independent reflections [2\u03b8\u226450.00\u00b0] and 1094 parameters.CCDC\u20051588114\u2005(1) 1588115\u2005(2) and 1588116\u2005(3) contain the supplementary crystallographic data for this paper. 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