{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,16]],"date-time":"2026-04-16T02:34:57Z","timestamp":1776306897486,"version":"3.50.1"},"reference-count":240,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2018,7,16]],"date-time":"2018-07-16T00:00:00Z","timestamp":1531699200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2018,8,6]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The chemistry of carbeniophosphines and phosphoniocarbenes, which have general structures derived formally from the three\u2010component \u201ccarbene\/phosphine\/positive charge\u201d association, is presented. These two complementary classes of carbon\u2013phosphorus\u2010based ligands, defined by the presence of an inverted cationic coordinating structure (C<jats:sup>+<\/jats:sup>\u223cP: vs. P<jats:sup>+<\/jats:sup>\u223cC:) have the common purpose of positioning a positive charge in the vicinity of the metal center. Through selected examples, the synthetic methods, coordination properties, and general reactivity of both cationic species is described. Particular emphasis is placed on the influence of the positive charge on the respective chemical behavior of the two classes of compound.<\/jats:p>","DOI":"10.1002\/asia.201800483","type":"journal-article","created":{"date-parts":[[2018,5,15]],"date-time":"2018-05-15T05:01:20Z","timestamp":1526360480000},"page":"1872-1887","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":23,"title":["Carbeniophosphines versus Phosphoniocarbenes: The Role of the Positive Charge"],"prefix":"10.1002","volume":"13","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3747-554X","authenticated-orcid":false,"given":"Yves","family":"Canac","sequence":"first","affiliation":[{"name":"LCC-CNRS Universit\u00e9 de Toulouse, CNRS, 205 route de Narbonne  31077 Toulouse Cedex 4 France"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,7,16]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(95)00508-N"},{"key":"e_1_2_7_2_1","unstructured":"For phosphine ligands see:"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2013.09.020"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2014.07.002"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703883"},{"key":"e_1_2_7_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200703883"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature13384"},{"key":"e_1_2_7_7_1","unstructured":"For phosphine ligands see:"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2004.06.024"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar800063t"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/b902238b"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00220"},{"key":"e_1_2_7_12_1","unstructured":"For phosphine ligands see:"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4GC01866D"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00031B"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900074m"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201000165"},{"key":"e_1_2_7_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201000165"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2dt32789a"},{"key":"e_1_2_7_18_1","unstructured":"\u00a0"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/C1NJ20808J"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201402375"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00262"},{"key":"e_1_2_7_22_1","unstructured":"\u00a0"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr940472u"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2004.02.005"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr800549j"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp057320v"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja026556z"},{"key":"e_1_2_7_28_1","unstructured":"Since in all cationic systems of typeA the positive charge is always in the \u03b1 position of the P atom the two designations \u201ccarbeniophosphine and \u03b1-cationic phosphine\u201d can be used in the present review."},{"key":"e_1_2_7_29_1","unstructured":"Amino(ylide)carbenes (AYCs) are not considered here because they are not formally part of the family of cationic carbenes. 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