{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,16]],"date-time":"2026-01-16T18:38:03Z","timestamp":1768588683880,"version":"3.49.0"},"reference-count":63,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2020,1,3]],"date-time":"2020-01-03T00:00:00Z","timestamp":1578009600000},"content-version":"am","delay-in-days":352,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#am"},{"start":{"date-parts":[[2019,1,16]],"date-time":"2019-01-16T00:00:00Z","timestamp":1547596800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100000923","name":"Australian Research Council","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000923","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100005156","name":"Alexander von Humboldt-Stiftung","doi-asserted-by":"publisher","award":["."],"award-info":[{"award-number":["."]}],"id":[{"id":"10.13039\/100005156","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000181","name":"Air Force Office of Scientific Research","doi-asserted-by":"publisher","award":["."],"award-info":[{"award-number":["."]}],"id":[{"id":"10.13039\/100000181","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2019,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Reactions of the beryllium dihalide complexes [BeX<jats:sub>2<\/jats:sub>(OEt<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>] (X=Br or I) with <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>,<jats:italic>N\u2032<\/jats:italic>,<jats:italic>N\u2032<\/jats:italic>\u2010tetramethylethylenediamine (TMEDA), a series of diazabutadienes, or bis(diphenylphosphino)methylene (DPPM) have yielded the chelated complexes, [BeX<jats:sub>2<\/jats:sub>(TMEDA)], [BeX<jats:sub>2<\/jats:sub>{(RN=CH)<jats:sub>2<\/jats:sub>}] (R=<jats:italic>t<\/jats:italic>Bu, mesityl (Mes), 2,6\u2010diethylphenyl (Dep) or 2,6\u2010diisopropylphenyl (Dip)), and the non\u2010chelated system, [BeI<jats:sub>2<\/jats:sub>(\u03ba<jats:sup>1<\/jats:sup>\u2010<jats:italic>P<\/jats:italic>\u2010DPPM)<jats:sub>2<\/jats:sub>]. Reactions of lithium or potassium salts of a variety of \u03b2\u2010diketiminates have given both three\u2010coordinate complexes, [{HC(RCNAr)<jats:sub>2<\/jats:sub>}BeX] (R=H or Me; Ar=Mes, Dep or Dip; X=Br or I); and four\u2010coordinate systems, [{HC(MeCNPh)<jats:sub>2<\/jats:sub>}BeBr(OEt<jats:sub>2<\/jats:sub>)] and [{HC(MeCNDip)(MeCNC<jats:sub>2<\/jats:sub>H<jats:sub>4<\/jats:sub>NMe<jats:sub>2<\/jats:sub>}BeI]. Alkali metal salts of ketiminate, guanidinate, boryl\/phosphinosilyl amide, or terphenyl ligands, lead to dimeric [{BeI{\u03bc\u2010[(OCMe)(DipNCMe)]CH}}<jats:sub>2<\/jats:sub>], and monomeric [{<jats:italic>i<\/jats:italic>Pr<jats:sub>2<\/jats:sub>NC(NMes)<jats:sub>2<\/jats:sub>}BeI(OEt<jats:sub>2<\/jats:sub>)], [\u03ba<jats:sup>2<\/jats:sup>\u2010<jats:italic>N,P<\/jats:italic>\u2010{(HCNDip)<jats:sub>2<\/jats:sub>B}(PPh<jats:sub>2<\/jats:sub>SiMe<jats:sub>2<\/jats:sub>)NBeI(OEt<jats:sub>2<\/jats:sub>)] and [{C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>Ph<jats:sub>2<\/jats:sub>\u20102,6}BeBr(OEt<jats:sub>2<\/jats:sub>)], respectively. Compound [{HC(MeCNPh)<jats:sub>2<\/jats:sub>}BeBr(OEt<jats:sub>2<\/jats:sub>)] undergoes a Schlenk redistribution reaction in solution, affording the homoleptic complex, [{HC(MeCNPh)<jats:sub>2<\/jats:sub>}<jats:sub>2<\/jats:sub>Be]. The majority of the prepared complexes have been characterized by X\u2010ray crystallography and multi\u2010nuclear NMR spectroscopy. The structures and stability of the complexes are discussed, as is their potential for use as precursors in poorly developed low oxidation state beryllium chemistry.<\/jats:p>","DOI":"10.1002\/asia.201801800","type":"journal-article","created":{"date-parts":[[2019,1,3]],"date-time":"2019-01-03T04:01:49Z","timestamp":1546488109000},"page":"486-490","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":45,"title":["Beryllium Halide Complexes Incorporating Neutral or Anionic Ligands: Potential Precursors for Beryllium Chemistry"],"prefix":"10.1002","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0309-0075","authenticated-orcid":false,"given":"Albert","family":"Paparo","sequence":"first","affiliation":[{"name":"School of Chemistry Monash University  P.O. Box 23 Melbourne VIC 3800 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7269-1045","authenticated-orcid":false,"given":"Cameron","family":"Jones","sequence":"additional","affiliation":[{"name":"School of Chemistry Monash University  P.O. Box 23 Melbourne VIC 3800 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2019,1,16]]},"reference":[{"key":"e_1_2_6_1_1","unstructured":"Selected reviews:"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100133q"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900375g"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470669266"},{"key":"e_1_2_6_5_1","unstructured":"Selected reviews:"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201800963"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00572"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00649G"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/C1SC00757B"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar2000875"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100216y"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/C0SC00388C"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature08634"},{"key":"e_1_2_6_14_1","unstructured":"\u00a0"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-017-0059"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-36270-5_3"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201604362"},{"key":"e_1_2_6_17_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201604362"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja808524y"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2542"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200902425"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic3022968"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/b801115j"},{"key":"e_1_2_6_23_1","unstructured":"See for example:"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8DT03963A"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201800177"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201803667"},{"key":"e_1_2_6_26_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201803667"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201610956"},{"key":"e_1_2_6_27_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201610956"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201703147"},{"key":"e_1_2_6_28_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201703147"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200800163"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1515\/znb-2003-0127"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201000418"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt51503f"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2014.11.008"},{"key":"e_1_2_6_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201601809"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201601809"},{"key":"e_1_2_6_35_1","first-page":"550","volume":"4","author":"Turova N. Y.","year":"1959","journal-title":"Russ. J. Inorg. Chem."},{"key":"e_1_2_6_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic970319t"},{"key":"e_1_2_6_37_1","doi-asserted-by":"publisher","DOI":"10.2116\/analsci.23.115"},{"key":"e_1_2_6_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic00032a012"},{"key":"e_1_2_6_39_1","unstructured":"\u00a0"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50075a015"},{"key":"e_1_2_6_41_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-2364(81)90191-8"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja046712x"},{"key":"e_1_2_6_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0065-3055(08)60052-0"},{"key":"e_1_2_6_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199413721"},{"key":"e_1_2_6_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19941061328"},{"key":"e_1_2_6_45_1","unstructured":"\u00a0"},{"key":"e_1_2_6_46_2","doi-asserted-by":"publisher","DOI":"10.5560\/ZNB.2011.66b0055"},{"key":"e_1_2_6_47_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-0682(199807)1998:7<905::AID-EJIC905>3.0.CO;2-Y"},{"key":"e_1_2_6_48_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201000172"},{"key":"e_1_2_6_49_2","doi-asserted-by":"publisher","DOI":"10.1039\/C39900000692"},{"key":"e_1_2_6_50_1","unstructured":"As determined from a survey of theCambridge Crystallographic Database December 2018."},{"key":"e_1_2_6_51_1","unstructured":"N.B. A related attempted synthesis of a beryllium amide from the reaction of [BeI2(OEt2)2] and [LiN(SiMe3)2] in diethyl ether instead led to the ether cleavage product [{(Et2O)(I)Be(\u03bc-OEt)}2] the X-ray crystal structure of which is described in the Supporting Information."},{"key":"e_1_2_6_52_1","first-page":"67","author":"Zhang R.-F.","year":"2014","journal-title":"J. Coord. Chem."},{"key":"e_1_2_6_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.6b00865"},{"key":"e_1_2_6_54_1","unstructured":"See for example:"},{"key":"e_1_2_6_55_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo01235a005"},{"key":"e_1_2_6_56_2","doi-asserted-by":"publisher","DOI":"10.1002\/pol.1959.1203412715"},{"key":"e_1_2_6_57_1","unstructured":"CCDC\u20051883617\u20131883629contain the supplementary crystallographic data for this paper. These data are provided free of charge byThe Cambridge Crystallographic Data Centre."}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fasia.201801800","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.201801800","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/asia.201801800","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/am-pdf\/10.1002\/asia.201801800","content-type":"application\/pdf","content-version":"am","intended-application":"syndication"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.201801800","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T17:25:46Z","timestamp":1759944346000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.201801800"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,1,16]]},"references-count":63,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2019,2]]}},"alternative-id":["10.1002\/asia.201801800"],"URL":"https:\/\/doi.org\/10.1002\/asia.201801800","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,1,16]]},"assertion":[{"value":"2018-12-06","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2019-01-16","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}