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Rietveld refinements of X\u2010ray and neutron powder diffraction patterns concluded that the oxide adopts a bixbyite type structure, crystallising in the cubic space group <jats:italic>Ia\u2010<\/jats:italic>3 with the unit cell parameter <jats:italic>a=<\/jats:italic>9.61164(4)\u2005\u00c5 at room temperature from powder neutron diffraction data. The cationic 8b and 24d sites were found to be occupationally disordered where both Cu and Sb could be found on both sites. This is supported by X\u2010ray absorption spectroscopy experiments showing more than one possible Cu environment. There was a significant net deficiency of oxygen in the compound which was first inferred from observations of a thermochromic\u2010like phenomena and also seen from <jats:italic>in situ<\/jats:italic> high temperature neutron diffraction experiments. Magnetic susceptibility and magnetization measurements show paramagnetic behaviour with spin\u2010glass like transition below 6\u2005K.<\/jats:p>","DOI":"10.1002\/asia.201801835","type":"journal-article","created":{"date-parts":[[2019,1,28]],"date-time":"2019-01-28T22:46:38Z","timestamp":1548715598000},"page":"1286-1292","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Synthesis and Structural Determination of the Disordered Bixbyite Cu<sub>3\u2010<i>x<\/i><\/sub>Sb<sub>1+<i>x<\/i><\/sub>O<sub>5.5+3<i>x<\/i>\/2<\/sub> with Spin\u2010Glass Behaviour"],"prefix":"10.1002","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2972-8519","authenticated-orcid":false,"given":"Martin","family":"Spasovski","sequence":"first","affiliation":[{"name":"School of Chemical Sciences &amp; Centre for Green Chemical Science University of Auckland  Private Bag 92019 Auckland 1142 New Zealand"},{"name":"MacDiarmid Institute of Advanced Materials and Nanotechnology Victoria University of Wellington  PO Box 600 Wellington New Zealand"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2366-5809","authenticated-orcid":false,"given":"Maxim","family":"Avdeev","sequence":"additional","affiliation":[{"name":"Australian Nuclear and Science Technology Organisation (ANSTO)  Locked Bag 2001 Kirrawee DC New South Wales 2232 Australia"},{"name":"School of Chemistry The University of Sydney  Sydney 2006 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4472-5807","authenticated-orcid":false,"given":"Tilo","family":"S\u00f6hnel","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences &amp; Centre for Green Chemical Science University of Auckland  Private Bag 92019 Auckland 1142 New Zealand"},{"name":"MacDiarmid Institute of Advanced Materials and Nanotechnology Victoria University of Wellington  PO Box 600 Wellington New Zealand"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2019,2,12]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1140362"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1369-7021(03)00332-8"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ssi.2004.07.036"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1515\/zkri-1930-0109"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRev.175.686"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0567740871002966"},{"key":"e_1_2_7_7_1","doi-asserted-by":"crossref","unstructured":"M. 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