{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,29]],"date-time":"2026-05-29T14:27:32Z","timestamp":1780064852671,"version":"3.54.0"},"reference-count":44,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2019,12,12]],"date-time":"2019-12-12T00:00:00Z","timestamp":1576108800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100010665","name":"H2020 Marie Sk\u0142odowska-Curie Actions","doi-asserted-by":"publisher","award":["642742"],"award-info":[{"award-number":["642742"]}],"id":[{"id":"10.13039\/100010665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100008530","name":"European Regional Development Fund","doi-asserted-by":"publisher","award":["MIS 5002409"],"award-info":[{"award-number":["MIS 5002409"]}],"id":[{"id":"10.13039\/501100008530","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2020,8,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A facile strategy for the controllable growth of CdS nanoparticles at the periphery of MoS<jats:sub>2<\/jats:sub> en route the preparation of electron donor\u2010acceptor nanoensembles is developed. Precisely, the carboxylic group of \u03b1\u2010lipoic acid, as addend of the modified MoS<jats:sub>2<\/jats:sub> obtained upon 1,2\u2010dithiolane functionalization, was employed as anchor site for the in situ preparation and immobilization of the CdS nanoparticles in an one\u2010pot two\u2010step process. The newly prepared MoS<jats:sub>2<\/jats:sub>\/CdS hybrid material was characterized by complementary spectroscopic, thermal and microscopy imaging means. Absorption spectroscopy was employed to register the formation of MoS<jats:sub>2<\/jats:sub>\/CdS, by observing a broad shoulder centered at 420\u2005nm due to CdS nanoparticles, while the excitonic bands of MoS<jats:sub>2<\/jats:sub> were also evident. Moreover, based on the efficient quenching of the characteristic fluorescence emission of CdS at 725\u2005nm by the presence of MoS<jats:sub>2<\/jats:sub>, strong electronic interactions at the excited state between the two species within the ensemble were identified. Photoelectrochemical assays of MoS<jats:sub>2<\/jats:sub>\/CdS thin\u2010film electrodes revealed a prompt, steady and reproducible anodic photoresponse during repeated on\u2010off cycles of illumination. A significant zero\u2010current photopotential of \u2212540\u2005mV and an anodic photocurrent of 1\u2005\u03bcA were observed, underlining improved charge\u2010separation and electron transport from CdS to MoS<jats:sub>2<\/jats:sub>. The superior performance of the charge\u2010transfer processes in MoS<jats:sub>2<\/jats:sub>\/CdS is of direct interest for the fabrication of photoelectrochemical and optoelectronic devices.<\/jats:p>","DOI":"10.1002\/asia.201901371","type":"journal-article","created":{"date-parts":[[2019,11,26]],"date-time":"2019-11-26T11:26:55Z","timestamp":1574767615000},"page":"2350-2356","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["In\u2010Situ Growth and Immobilization of CdS Nanoparticles onto Functionalized MoS<sub>2<\/sub>: Preparation, Characterization and Fabrication of Photoelectrochemical Cells"],"prefix":"10.1002","volume":"15","author":[{"given":"Antonia","family":"Kagkoura","sequence":"first","affiliation":[{"name":"Theoretical and Physical Chemistry Institute National Hellenic Research Foundation  48 Vassileos Constantinou Avenue Athens 11635 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