{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T09:37:33Z","timestamp":1790501853220,"version":"4.1.0"},"reference-count":117,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2020,2,17]],"date-time":"2020-02-17T00:00:00Z","timestamp":1581897600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2020,3,16]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Selective hydrogenation of nitriles and alkynes is crucial considering the vast applications of reduced products in industries and in the synthesis of bioactive compounds. Particularly, the late 3d transition metal catalysts (manganese, iron, cobalt, nickel and copper) have shown promising activity for the hydrogenation of nitriles to primary amines, secondary amines and imines. Similarly, semihydrogenation of alkynes to\n                    <jats:italic>E<\/jats:italic>\n                    \u2010 and\n                    <jats:italic>Z<\/jats:italic>\n                    \u2010alkenes by 3d metals is adequately successful both via the transfer hydrogenation and by using molecular hydrogen. The emergence of 3d transition metals in the selective synthesis of industrially relevant amines, imines and alkenes makes this protocol more attractive. Herein, we provide a concise overview on the late 3d transition metal\u2010catalyzed hydrogenation of nitriles to amines and imines as well as semihydrogenation of alkynes to alkenes.\n                  <\/jats:p>","DOI":"10.1002\/asia.201901762","type":"journal-article","created":{"date-parts":[[2020,2,7]],"date-time":"2020-02-07T01:48:35Z","timestamp":1581040115000},"page":"690-708","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":72,"title":["3\u2009d Transition Metal\u2010Catalyzed Hydrogenation of Nitriles and Alkynes"],"prefix":"10.1002","volume":"15","author":[{"given":"Dipesh M.","family":"Sharma","sequence":"first","affiliation":[{"name":"Chemical Engineering Division CSIR-National Chemical Laboratory (CSIR-NCL) Academy of Scientific and Innovative Research (AcSIR)  Dr. Homi Bhabha Road Pune 411 008 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9257-5236","authenticated-orcid":false,"given":"Benudhar","family":"Punji","sequence":"additional","affiliation":[{"name":"Chemical Engineering Division CSIR-National Chemical Laboratory (CSIR-NCL) Academy of Scientific and Innovative Research (AcSIR)  Dr. Homi Bhabha Road Pune 411 008 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,2,17]]},"reference":[{"key":"e_1_2_7_1_1","volume-title":"Catalytic Hydrogenation","author":"Cerveny L.","year":"1986"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/9783527619191"},{"key":"e_1_2_7_3_1","doi-asserted-by":"crossref","unstructured":"J. G. Vries 2007 Handbook of Homogeneous Hydrogenation; Wiley-VCH: Weinheim","DOI":"10.1002\/9783527619382"},{"key":"e_1_2_7_4_1","unstructured":"P. G. Andersson I. J. Munslow 2008 Weinheim"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr00066a003"},{"key":"e_1_2_7_6_1","unstructured":"E. Farnetti R. Di\u2005Monte J. Ka\u0161par Inorganic and Bio-inorganic Chemistry Vol II: Homogeneous and Heterogeneous Catalysis 50\u201386."},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1381-1169(02)00728-8"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr60281a003"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35410A"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/op4003278"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr400609m"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00038F"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr300527g"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500425u"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b00072"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00262"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00334J"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00404"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00555"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/a808142e"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF02234899"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2004.08.025"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jm0512903"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/np1004278"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol300476f"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo300225z"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-1973-22234"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201400940"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00203"},{"key":"e_1_2_7_30_1","doi-asserted-by":"crossref","first-page":"515","DOI":"10.1021\/bk-1991-0443.ch041","volume-title":"Synthesis and Chemistry of Agrochemicals II, Vol. 443","author":"Urch C. J.","year":"1991"},{"key":"e_1_2_7_31_1","unstructured":"S.\u2005A. Lawrence Amines: Synthesis Properties and Application Cambridge University Press Cambridge2004."},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.200505158"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1186\/1475-2832-3-2"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1365-2125.2006.02641.x"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.biopha.2018.12.085"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201803016"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b02869"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-0035-1562791"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.2174\/138527212800194692"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-0036-1590818"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00149"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20011015)40:20<3750::AID-ANIE3750>3.0.CO;2-6"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2012.12.035"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic9010218"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic1004424"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2016.04.007"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b03709"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b03132"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201901040"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b03899"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201901154"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms5111"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201200159"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CY00834H"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC08204H"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201608537"},{"key":"e_1_2_7_56_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201608537"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b00906"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b04879"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201502418"},{"key":"e_1_2_7_59_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201502418"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201601843"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b07368"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b02645"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CY00225A"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1021\/om0600644"},{"key":"e_1_2_7_65_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b02744"},{"key":"e_1_2_7_66_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201608345"},{"key":"e_1_2_7_66_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201608345"},{"key":"e_1_2_7_67_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201900586"},{"key":"e_1_2_7_68_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2009.05.027"},{"key":"e_1_2_7_69_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.7b00545"},{"key":"e_1_2_7_70_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4RA11193A"},{"key":"e_1_2_7_71_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2009.09.164"},{"key":"e_1_2_7_72_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr3001753"},{"key":"e_1_2_7_73_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00243a043"},{"key":"e_1_2_7_74_1","doi-asserted-by":"publisher","DOI":"10.15227\/orgsyn.046.0089"},{"key":"e_1_2_7_75_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201506075"},{"key":"e_1_2_7_75_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201506075"},{"key":"e_1_2_7_76_1","doi-asserted-by":"publisher","DOI":"10.1039\/a905765j"},{"key":"e_1_2_7_77_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC09714C"},{"key":"e_1_2_7_78_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC08163C"},{"key":"e_1_2_7_79_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b10357"},{"key":"e_1_2_7_80_1","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.201800314"},{"key":"e_1_2_7_81_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7QO00613F"},{"key":"e_1_2_7_82_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b00983"},{"key":"e_1_2_7_83_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja071159f"},{"key":"e_1_2_7_84_1","doi-asserted-by":"publisher","DOI":"10.1021\/om00110a048"},{"key":"e_1_2_7_85_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201000941"},{"key":"e_1_2_7_86_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201100233"},{"key":"e_1_2_7_87_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc31091k"},{"key":"e_1_2_7_88_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc31395b"},{"key":"e_1_2_7_89_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CY00681D"},{"key":"e_1_2_7_90_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(97)10790-0"},{"key":"e_1_2_7_91_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201306629"},{"key":"e_1_2_7_91_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201306629"},{"key":"e_1_2_7_92_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201906971"},{"key":"e_1_2_7_93_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b09907"},{"key":"e_1_2_7_94_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b02272"},{"key":"e_1_2_7_95_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b04271"},{"key":"e_1_2_7_96_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CY01994G"},{"key":"e_1_2_7_97_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC01970G"},{"key":"e_1_2_7_98_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b08128"},{"key":"e_1_2_7_99_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC01228D"},{"key":"e_1_2_7_100_1","doi-asserted-by":"publisher","DOI":"10.1039\/C39730000553"},{"key":"e_1_2_7_101_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2010.06.052"},{"key":"e_1_2_7_102_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.5b01047"},{"key":"e_1_2_7_103_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201200200"},{"key":"e_1_2_7_104_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol4001679"},{"key":"e_1_2_7_105_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201300916"},{"key":"e_1_2_7_106_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC09067B"},{"key":"e_1_2_7_107_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-0034-1379896"},{"key":"e_1_2_7_108_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201501739"},{"key":"e_1_2_7_109_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6OB02271E"},{"key":"e_1_2_7_110_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.6b00126"},{"key":"e_1_2_7_111_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo00207a056"},{"key":"e_1_2_7_112_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201007876"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fasia.201901762","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.201901762","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/asia.201901762","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.201901762","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,9]],"date-time":"2025-10-09T01:59:42Z","timestamp":1759975182000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.201901762"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,2,17]]},"references-count":117,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2020,3,16]]}},"alternative-id":["10.1002\/asia.201901762"],"URL":"https:\/\/doi.org\/10.1002\/asia.201901762","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,2,17]]},"assertion":[{"value":"2019-12-16","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-02-17","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}