{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,17]],"date-time":"2026-01-17T06:49:26Z","timestamp":1768632566233,"version":"3.49.0"},"reference-count":41,"publisher":"Wiley","issue":"16","license":[{"start":{"date-parts":[[2021,6,17]],"date-time":"2021-06-17T00:00:00Z","timestamp":1623888000000},"content-version":"am","delay-in-days":350,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#am"},{"start":{"date-parts":[[2020,7,2]],"date-time":"2020-07-02T00:00:00Z","timestamp":1593648000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100000923","name":"Australian Research Council","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000923","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2020,8,17]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Reaction of a lithium boryl, [(THF)<jats:sub>2<\/jats:sub>Li{B(DAB)}] (DAB=[(DipNCH)<jats:sub>2<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup>, Dip=2,6\u2010diisopropylphenyl), with a dinuclear magnesium(I) compound [{(<jats:sup>Mes<\/jats:sup>Nacnac)Mg}<jats:sub>2<\/jats:sub>] (<jats:sup>Mes<\/jats:sup>Nacnac=[HC(MeCNMes)<jats:sub>2<\/jats:sub>]<jats:sup>\u2212<\/jats:sup>, Mes=mesityl) unexpectedly afforded a rare example of a terminal magnesium boryl species, [(<jats:sup>Mes<\/jats:sup>Nacnac)(THF)Mg{B(DAB)}]. Attempts to prepare the magnesium boryl via a salt metathesis reaction between the lithium boryl and a \u03b2\u2010diketiminato magnesium iodide compound, instead led to an intractable mixture of products. Similarly, reaction of the lithium boryl with a \u03b2\u2010diketiminato beryllium bromide precursor, [(<jats:sup>Dep<\/jats:sup>Nacnac)BeBr] (Dep=2,6\u2010diethylphenyl) did not give a beryllium boryl, but instead afforded an unprecedented example of a beryllium substituted diazaborole heterocycle, [{(<jats:sup>Dep<\/jats:sup>Nacnac)Be(4\u2010DAB<jats:sup>\u2212H<\/jats:sup>)}BBr]. For sake of comparison, the same group 2 halide precursor compounds were treated with a potassium gallyl analogue of the lithium boryl, <jats:italic>viz<\/jats:italic>. [(tmeda)K{:Ga(DAB)}] (tmeda=<jats:italic>N,N,N\u2019,N\u2019<\/jats:italic>\u2010tetramethylethylenediamine), but no reactions were observed.<\/jats:p>","DOI":"10.1002\/asia.202000662","type":"journal-article","created":{"date-parts":[[2020,6,18]],"date-time":"2020-06-18T01:31:29Z","timestamp":1592443889000},"page":"2447-2450","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Synthesis and Characterization of a Magnesium Boryl and a Beryllium\u2010Substituted Diazaborole"],"prefix":"10.1002","volume":"15","author":[{"given":"Deepak","family":"Dange","sequence":"first","affiliation":[{"name":"School of Chemistry Monash University  PO Box 23 Melbourne VIC 3800 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Albert","family":"Paparo","sequence":"additional","affiliation":[{"name":"School of Chemistry Monash University  PO Box 23 Melbourne VIC 3800 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7269-1045","authenticated-orcid":false,"given":"Cameron","family":"Jones","sequence":"additional","affiliation":[{"name":"School of Chemistry Monash University  PO Box 23 Melbourne VIC 3800 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2020,7,2]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1131914"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-319-13054-5_1"},{"key":"e_1_2_2_3_1","unstructured":"As determined from a survey of the Cambridge Crystallographic Database June 2020."},{"key":"e_1_2_2_4_1","unstructured":"\u00a0"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1870"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja301042u"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC01772F"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b00710"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja5062467"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201812675"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC08449D"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201708496"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC00697F"},{"key":"e_1_2_2_14_1","unstructured":"\u00a0"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-017-0059"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-36270-5_3"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0dt01831g"},{"key":"e_1_2_2_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja073037t"},{"key":"e_1_2_2_19_1","unstructured":"\u00a0"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC08519A"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b03263"},{"key":"e_1_2_2_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b03432"},{"key":"e_1_2_2_23_1","unstructured":"\u00a0"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms15022"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC04294F"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8DT01451E"},{"key":"e_1_2_2_27_1","unstructured":"\u00a0"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b04085"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC00836B"},{"key":"e_1_2_2_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200803960"},{"key":"e_1_2_2_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200902425"},{"key":"e_1_2_2_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/b206605j"},{"key":"e_1_2_2_33_1","unstructured":"\u00a0"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/om1001606"},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic060136j"},{"key":"e_1_2_2_36_1","unstructured":"N.\u2005B. In an attempt to form a monodentate boryl\/silyl substituted amido-magnesium iodide complex viz. [(TBoN)MgI] (TBoN=-N(SiMe3){B(DAB)}) to react with [(THF)2Li{B(DAB)] the homoleptic complex [Mg(TBoN)2] was instead formed. Details of its synthesis spectroscopic characterization and crystal structure can be found in the Supporting Information."},{"key":"e_1_2_2_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201801800"},{"key":"e_1_2_2_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr100216y"},{"key":"e_1_2_2_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic801424k"},{"key":"e_1_2_2_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2007.02.014"},{"key":"e_1_2_2_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7DT04079B"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fasia.202000662","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202000662","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/asia.202000662","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/am-pdf\/10.1002\/asia.202000662","content-type":"application\/pdf","content-version":"am","intended-application":"syndication"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202000662","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T13:25:25Z","timestamp":1759929925000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.202000662"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,7,2]]},"references-count":41,"journal-issue":{"issue":"16","published-print":{"date-parts":[[2020,8,17]]}},"alternative-id":["10.1002\/asia.202000662"],"URL":"https:\/\/doi.org\/10.1002\/asia.202000662","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,7,2]]},"assertion":[{"value":"2020-06-04","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-07-02","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}