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This review briefly introduces the basic principles and influencing factors of [(001)\u2010(101)\u2010TiO<jats:sub>2<\/jats:sub>]. On this basis, the effect of heterostructures formed by different materials and modification methods on its photocatalytic activity are elaborated in detail. Mainly formed heterostructures mentioned in this review include oxygen vacancy\/Ti<jats:sup>3+<\/jats:sup>\u2010[(001)\u2010(101)\u2010TiO<jats:sub>2<\/jats:sub>] heterostructures, noble metal\u2010[(001)\u2010(101)\u2010TiO<jats:sub>2<\/jats:sub>] heterostructures, metal sulfide\u2010[(001)\u2010(101)\u2010TiO<jats:sub>2<\/jats:sub>] heterostructures, metal oxide\u2010[(001)\u2010(101)\u2010TiO<jats:sub>2<\/jats:sub>] heterostructures and carbon material\u2010[(001)\u2010(101)\u2010TiO<jats:sub>2<\/jats:sub>] heterostructures. The light absorption range and charge separation mechanism of (001)\u2010(101)\u2010TiO<jats:sub>2<\/jats:sub> after modification are discussed. 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