{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,15]],"date-time":"2025-10-15T18:03:43Z","timestamp":1760551423450,"version":"build-2065373602"},"reference-count":63,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2021,5,18]],"date-time":"2021-05-18T00:00:00Z","timestamp":1621296000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21773051","22072035","21801056","21901056"],"award-info":[{"award-number":["21773051","22072035","21801056","21901056"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2021,7,5]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Organosilicon compounds are important reagents and synthetic intermediates that play a key role in the construction of new materials and complex products. Here we show a highly diastereoselective rhodium\u2010catalyzed cycloisomerization of 1,6\u2010dienes, in which the use of (EtO)<jats:sub>3<\/jats:sub>SiH accelerates the intramolecular cyclization reaction to afford a novel spiro\u2010fused succinimide and pyrazolone derivatives in moderate to excellent yields as a single diastereoisomer. The proposed mechanism involves an active Rh\u2212H species from the hydrosilane that is the H\u2010donor in this spiro\u2010type cycloisomerization reaction.<\/jats:p>","DOI":"10.1002\/asia.202100372","type":"journal-article","created":{"date-parts":[[2021,5,4]],"date-time":"2021-05-04T09:32:04Z","timestamp":1620120724000},"page":"1730-1734","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Highly Diastereoselective Hydrosilane\u2010Assisted Rhodium\u2010Catalyzed Spiro\u2010Type Cycloisomerization of Succinimide and Pyrazolone\u2010Based Functional 1,6\u2010Dienes"],"prefix":"10.1002","volume":"16","author":[{"given":"Hui\u2010Lin","family":"Li","sequence":"first","affiliation":[{"name":"Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education and Laboratory of Organosilicon Material Technology of Zhejiang Province College of Material, Chemistry and Chemical Engineering Hangzhou Normal University  Hangzhou 311121 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wei\u2010Sheng","family":"Huang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education and Laboratory of Organosilicon Material Technology of Zhejiang Province College of Material, Chemistry and Chemical Engineering Hangzhou Normal University  Hangzhou 311121 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Fang\u2010Ying","family":"Ling","sequence":"additional","affiliation":[{"name":"Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education and Laboratory of Organosilicon Material Technology of Zhejiang Province College of Material, Chemistry and Chemical Engineering Hangzhou Normal University  Hangzhou 311121 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Li","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education and Laboratory of Organosilicon Material Technology of Zhejiang Province College of Material, Chemistry and Chemical Engineering Hangzhou Normal University  Hangzhou 311121 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jun\u2010Hao","family":"Yan","sequence":"additional","affiliation":[{"name":"Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education and Laboratory of Organosilicon Material Technology of Zhejiang Province College of Material, Chemistry and Chemical Engineering Hangzhou Normal University  Hangzhou 311121 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hao","family":"Xu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education and Laboratory of Organosilicon Material Technology of Zhejiang Province College of Material, Chemistry and Chemical Engineering Hangzhou Normal University  Hangzhou 311121 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5705-0015","authenticated-orcid":false,"given":"Li\u2010Wen","family":"Xu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education and Laboratory of Organosilicon Material Technology of Zhejiang Province College of Material, Chemistry and Chemical Engineering Hangzhou Normal University  Hangzhou 311121 P. R. China"},{"name":"State Key Laboratory for Oxo Synthesis and Selective Oxidation Suzhou Research Institute (SRI), Lanzhou Institute of Chemical Physics (LICP) University of the Chinese Academy of Sciences (UCAS)  Lanzhou 730000 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2021,5,18]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"crossref","first-page":"4736","DOI":"10.1021\/cr300050n","volume":"112","author":"Yamamoto Y.","year":"2012","journal-title":"Chem. Rev."},{"key":"e_1_2_2_2_1","unstructured":"\u00a0"},{"key":"e_1_2_2_3_2","doi-asserted-by":"crossref","first-page":"8007","DOI":"10.1021\/ja9738788","volume":"120","author":"Radetich B.","year":"1998","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_2_4_2","doi-asserted-by":"crossref","first-page":"1537","DOI":"10.1002\/adsc.200505176","volume":"347","author":"B\u00f6ig C.","year":"2005","journal-title":"Adv. Synth. Catal."},{"key":"e_1_2_2_5_2","doi-asserted-by":"crossref","first-page":"268","DOI":"10.1016\/j.chempr.2017.07.010","volume":"3","author":"Kuang Y.","year":"2017","journal-title":"Chem."},{"key":"e_1_2_2_6_1","unstructured":"\u00a0"},{"key":"e_1_2_2_7_2","doi-asserted-by":"crossref","first-page":"10017","DOI":"10.1021\/ja001730+","volume":"122","author":"Kisanga P.","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_2_8_2","doi-asserted-by":"crossref","first-page":"5261","DOI":"10.1002\/anie.201814558","volume":"58","author":"Kochi T.","year":"2019","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_2_8_3","doi-asserted-by":"crossref","first-page":"5315","DOI":"10.1002\/ange.201814558","volume":"131","year":"2019","journal-title":"Angew. Chem."},{"key":"e_1_2_2_9_2","doi-asserted-by":"crossref","first-page":"1103","DOI":"10.1021\/ol9908981","volume":"7","author":"Widenhoefer R. A.","year":"1999","journal-title":"Org. Lett."},{"key":"e_1_2_2_10_1","unstructured":"\u00a0"},{"key":"e_1_2_2_11_2","doi-asserted-by":"crossref","first-page":"6372","DOI":"10.1021\/ja010134s","volume":"123","author":"Yamamoto Y.","year":"2001","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_2_12_2","doi-asserted-by":"crossref","first-page":"15592","DOI":"10.1021\/acs.inorgchem.8b02917","volume":"57","author":"Ivery E.","year":"2018","journal-title":"Inorg. Chem."},{"key":"e_1_2_2_13_2","doi-asserted-by":"crossref","first-page":"231","DOI":"10.1002\/chem.200305340","volume":"10","author":"Yamamoto Y.","year":"2004","journal-title":"Chem. Eur. J."},{"key":"e_1_2_2_14_1","doi-asserted-by":"crossref","first-page":"1223","DOI":"10.1021\/ja9922680","volume":"122","author":"Okamoto S.","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_2_15_1","unstructured":"\u00a0"},{"key":"e_1_2_2_16_2","doi-asserted-by":"crossref","first-page":"7285","DOI":"10.1002\/anie.200602020","volume":"45","author":"Grau F.","year":"2006","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_2_16_3","doi-asserted-by":"crossref","first-page":"7443","DOI":"10.1002\/ange.200602020","volume":"118","year":"2006","journal-title":"Angew. Chem."},{"key":"e_1_2_2_17_2","doi-asserted-by":"crossref","first-page":"581","DOI":"10.1021\/jacs.9b11909","volume":"142","author":"Liu Z. Y.","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_2_18_1","doi-asserted-by":"crossref","first-page":"2379","DOI":"10.1055\/s-0034-1378531","volume":"25","author":"A\u00efssa C.","year":"2004","journal-title":"Synlett"},{"key":"e_1_2_2_18_2","doi-asserted-by":"crossref","first-page":"3320","DOI":"10.1055\/s-0037-1611832","volume":"51","author":"Liu J.","year":"2019","journal-title":"Synthesis."},{"key":"e_1_2_2_19_1","unstructured":"\u00a0"},{"key":"e_1_2_2_20_2","doi-asserted-by":"crossref","first-page":"27","DOI":"10.1039\/c39800000027","author":"Grigg R.","year":"1980","journal-title":"J. Chem. Soc. Chem. Commun."},{"key":"e_1_2_2_21_2","doi-asserted-by":"crossref","first-page":"3310","DOI":"10.1021\/jacs.6b01445","volume":"138","author":"Park J. W.","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_2_22_2","doi-asserted-by":"crossref","first-page":"395","DOI":"10.1021\/jo035551x","volume":"69","author":"Makino T.","year":"2004","journal-title":"J. Org. Chem."},{"key":"e_1_2_2_23_2","doi-asserted-by":"crossref","first-page":"4209","DOI":"10.1002\/anie.201400080","volume":"53","author":"A\u00efssa C.","year":"2014","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_2_23_3","doi-asserted-by":"crossref","first-page":"4293","DOI":"10.1002\/ange.201400080","volume":"126","year":"2014","journal-title":"Angew. Chem."},{"key":"e_1_2_2_24_1","doi-asserted-by":"crossref","first-page":"712","DOI":"10.1039\/c29710000712","author":"Bright A.","year":"1971","journal-title":"J. Chem. Soc. D."},{"key":"e_1_2_2_25_1","unstructured":"\u00a0"},{"key":"e_1_2_2_26_2","first-page":"185","volume":"318","author":"Schmitz E.","year":"1976","journal-title":"Chem."},{"key":"e_1_2_2_27_2","first-page":"471","volume":"318","author":"Schmitz E.","year":"1976","journal-title":"Chem."},{"key":"e_1_2_2_28_1","doi-asserted-by":"crossref","first-page":"1745","DOI":"10.1039\/p19840001745","volume":"1","author":"Grigg R.","year":"1984","journal-title":"J. Chem. Soc.-Perkin Trans."},{"key":"e_1_2_2_29_1","unstructured":"\u00a0"},{"key":"e_1_2_2_30_2","doi-asserted-by":"crossref","first-page":"2904","DOI":"10.1038\/s41467-020-16716-5","volume":"11","author":"Gu X. W.","year":"2020","journal-title":"Nat. Commun."},{"key":"e_1_2_2_31_2","doi-asserted-by":"crossref","first-page":"3478","DOI":"10.6023\/cjoc202000067","volume":"40","author":"He Q. X.","year":"2020","journal-title":"Chin. J. Org. Chem."},{"key":"e_1_2_2_32_2","doi-asserted-by":"crossref","first-page":"17994","DOI":"10.1002\/anie.201908837","volume":"58","author":"Li F.","year":"2019","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_2_33_2","doi-asserted-by":"crossref","first-page":"790","DOI":"10.1002\/anie.201913060","volume":"59","author":"Wang X. B.","year":"2020","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_2_33_3","doi-asserted-by":"crossref","first-page":"800","DOI":"10.1002\/ange.201913060","volume":"132","year":"2020","journal-title":"Angew. Chem."},{"key":"e_1_2_2_34_2","doi-asserted-by":"crossref","first-page":"1080","DOI":"10.6023\/cjoc202000019","volume":"40","author":"Wang X. C.","year":"2020","journal-title":"Chin. J. Org. Chem."},{"key":"e_1_2_2_35_1","unstructured":"\u00a0"},{"key":"e_1_2_2_36_2","doi-asserted-by":"crossref","first-page":"7986","DOI":"10.1021\/jo901513v","volume":"74","author":"Sumida Y.","year":"2009","journal-title":"J. Org. Chem."},{"key":"e_1_2_2_37_2","doi-asserted-by":"crossref","first-page":"9110","DOI":"10.1021\/acscatal.9b02623","volume":"9","author":"Zhao Z. Y.","year":"2019","journal-title":"ACS Catal."},{"key":"e_1_2_2_38_2","doi-asserted-by":"crossref","first-page":"873","DOI":"10.6023\/cjoc201911009","volume":"40","author":"Zhang H. M.","year":"2020","journal-title":"Chin. J. Org. Chem."},{"key":"e_1_2_2_39_2","doi-asserted-by":"crossref","first-page":"1177","DOI":"10.6023\/cjoc201910012","volume":"40","author":"Dai Z. N.","year":"2020","journal-title":"Chin. J. Org. Chem."},{"key":"e_1_2_2_40_1","unstructured":"For our recent account see:"},{"key":"e_1_2_2_41_2","doi-asserted-by":"crossref","first-page":"21","DOI":"10.1055\/s-0039-1691496","volume":"31","author":"Li L.","year":"2020","journal-title":"Synlett"},{"key":"e_1_2_2_42_2","doi-asserted-by":"crossref","first-page":"4188","DOI":"10.1039\/D0CC00844C","volume":"56","author":"Long P. W.","year":"2020","journal-title":"Chem. Commun."},{"key":"e_1_2_2_43_2","doi-asserted-by":"crossref","first-page":"1082","DOI":"10.1007\/s11426-020-9768-x","volume":"63","author":"Ma J.-H.","year":"2020","journal-title":"Sci. China Chem."},{"key":"e_1_2_2_44_2","doi-asserted-by":"crossref","first-page":"9110","DOI":"10.1021\/acscatal.9b02623","volume":"9","author":"Zhao Z. Y.","year":"2019","journal-title":"ACS Catal."},{"key":"e_1_2_2_45_1","doi-asserted-by":"crossref","first-page":"11291","DOI":"10.1021\/acs.chemrev.5b00559","volume":"116","author":"Corey J. Y.","year":"2016","journal-title":"Chem. Rev."},{"key":"e_1_2_2_46_1","unstructured":"\u00a0"},{"key":"e_1_2_2_47_2","doi-asserted-by":"crossref","first-page":"1797","DOI":"10.1002\/anie.201510602","volume":"55","author":"Hack D.","year":"2016","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_2_47_3","doi-asserted-by":"crossref","first-page":"1829","DOI":"10.1002\/ange.201510602","volume":"128","year":"2016","journal-title":"Angew. Chem."},{"key":"e_1_2_2_48_2","doi-asserted-by":"crossref","first-page":"14354","DOI":"10.1021\/jacs.6b08236","volume":"138","author":"Lin H. C.","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_2_49_2","doi-asserted-by":"crossref","first-page":"5643","DOI":"10.1002\/anie.201311214","volume":"53","author":"Han X.","year":"2014","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_2_49_3","doi-asserted-by":"crossref","first-page":"5749","DOI":"10.1002\/ange.201311214","volume":"126","year":"2014","journal-title":"Angew. Chem."},{"key":"e_1_2_2_50_2","doi-asserted-by":"crossref","first-page":"9255","DOI":"10.1021\/ja402740q","volume":"135","author":"Tao Z. L.","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_2_51_1","unstructured":"\u00a0"},{"key":"e_1_2_2_52_2","doi-asserted-by":"crossref","first-page":"554","DOI":"10.1002\/chem.201405420","volume":"21","author":"Song T.","year":"2015","journal-title":"Chem. Eur. J."},{"key":"e_1_2_2_53_2","doi-asserted-by":"crossref","first-page":"58698","DOI":"10.1039\/C6RA13687G","volume":"6","author":"Chen M. Y.","year":"2016","journal-title":"RSC Adv."},{"key":"e_1_2_2_54_2","doi-asserted-by":"crossref","first-page":"280","DOI":"10.1002\/cctc.201701336","volume":"10","author":"Chen M. Y.","year":"2018","journal-title":"ChemCatChem."},{"key":"e_1_2_2_55_2","doi-asserted-by":"crossref","first-page":"101268","DOI":"10.1016\/j.isci.2020.101268","volume":"23","author":"Tang R. H.","year":"2020","journal-title":"iScience"},{"key":"e_1_2_2_56_2","doi-asserted-by":"crossref","first-page":"452","DOI":"10.1021\/acs.accounts.0c00740","volume":"54","author":"Ye F.","year":"2021","journal-title":"Acc. Chem. Res."}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202100372","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/asia.202100372","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202100372","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T12:56:27Z","timestamp":1759928187000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.202100372"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,5,18]]},"references-count":63,"journal-issue":{"issue":"13","published-print":{"date-parts":[[2021,7,5]]}},"alternative-id":["10.1002\/asia.202100372"],"URL":"https:\/\/doi.org\/10.1002\/asia.202100372","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"type":"print","value":"1861-4728"},{"type":"electronic","value":"1861-471X"}],"subject":[],"published":{"date-parts":[[2021,5,18]]},"assertion":[{"value":"2021-04-09","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2021-05-18","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}