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However, to make these TiO<jats:sub>2<\/jats:sub> surface complexes durable, integrating 2,2,6,6\u2010tetramethylpiperidine\u20101\u2010oxyl (TEMPO) or its analogues as a redox mediator with photocatalysis is the key to constructing selective chemical transformations. Herein, sodium 6,7\u2010dihydroxynaphthalene\u20102\u2010sulfonate (DHNS) was obtained by extending the \u03c0\u2010conjugated system of catechol by adding a benzene ring and a substituent sodium sulfonate (\u2212SO<jats:sub>3<\/jats:sub><jats:sup>\u2212<\/jats:sup>Na<jats:sup>+<\/jats:sup>). The DHNS\u2212TiO<jats:sub>2<\/jats:sub> showed the best photocatalytic activity towards the blue light\u2010induced selective aerobic oxidation of benzylamine. Compared to TEMPO, 4\u2010amino\u20102,2,6,6\u2010tetramethylpiperidine\u20101\u2010oxyl (4\u2010amino\u2010TEMPO) could rise above 70% in conversion of benzylamine over the DHNS\u2212TiO<jats:sub>2<\/jats:sub> photocatalyst. Eventually, a wide range of amines could be selectively oxidized into imines with atmospheric O<jats:sub>2<\/jats:sub> by cooperative photocatalysis of DHNS\u2212TiO<jats:sub>2<\/jats:sub> with 4\u2010amino\u2010TEMPO. Notably, superoxide (O<jats:sub>2<\/jats:sub><jats:sup>\u2022\u2212<\/jats:sup>) is crucial in coupling the photocatalytic cycle of DHNS\u2212TiO<jats:sub>2<\/jats:sub> and the redox cycle of 4\u2010amino\u2010TEMPO. This work underscores the design of surface ligands for semiconductors and the selection of a redox mediator in visible light photocatalysis for selective chemical transformations.<\/jats:p>","DOI":"10.1002\/asia.202100682","type":"journal-article","created":{"date-parts":[[2021,7,23]],"date-time":"2021-07-23T23:23:29Z","timestamp":1627082609000},"page":"2659-2668","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Cooperative Photocatalysis with 4\u2010Amino\u2010TEMPO for Selective Aerobic Oxidation of Amines over TiO<sub>2<\/sub> Nanotubes"],"prefix":"10.1002","volume":"16","author":[{"given":"Yuexin","family":"Wang","sequence":"first","affiliation":[{"name":"Sauvage Center for Molecular Sciences College of Chemistry and Molecular Sciences Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Zhou","sequence":"additional","affiliation":[{"name":"Sauvage 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