{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,18]],"date-time":"2026-05-18T10:11:02Z","timestamp":1779099062850,"version":"3.51.4"},"reference-count":58,"publisher":"Wiley","issue":"20","license":[{"start":{"date-parts":[[2021,8,25]],"date-time":"2021-08-25T00:00:00Z","timestamp":1629849600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21902094"],"award-info":[{"award-number":["21902094"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2020M683405"],"award-info":[{"award-number":["2020M683405"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011192","name":"Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100011192","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2021,10,18]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The development of efficient, stable, and cost\u2010effective heterogeneous catalysts for catalytic transfer hydrogenation (CTH) of biomass\u2010derived furfural (FAL) is highly desired. Herein, series of N\u2010doped graphitic carbon embedded CoNi bimetallic alloy nanoparticles were fabricated and used for the CTH of FAL to value\u2010added furfuryl alcohol (FOL) with renewable isopropanol as hydrogen donor. Intrinsic catalytic activity examination indicated the catalytic performance of Ni<jats:sub>x<\/jats:sub>Co<jats:sub>y<\/jats:sub>@NGC (x:y=1\u2009:\u20093, 1\u2009:\u20091, 3\u2009:\u20091) nanocatalysts were sensitive to their chemical compositions. The optimal Ni<jats:sub>1<\/jats:sub>Co<jats:sub>1<\/jats:sub>@NGC nanocatalyst with Ni\/Co mole ratio of 1\u2009:\u20091 afforded a largest FOL yield of 89.3% with nearly full conversion of FAL. The synergistic effect enabled by bimetallic alloys and the abundant N\u2010based Lewis base sites and surface Co\u2212N active species were revealed based on systematic structural characterization, responsible for the excellent catalytic efficiency of bimetallic Ni<jats:sub>1<\/jats:sub>Co<jats:sub>1<\/jats:sub>@NGC nanocatalyst for CTH of FAL.<\/jats:p>","DOI":"10.1002\/asia.202100727","type":"journal-article","created":{"date-parts":[[2021,8,16]],"date-time":"2021-08-16T23:37:11Z","timestamp":1629157031000},"page":"3194-3201","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":34,"title":["Highly Dispersed CoNi Alloy Embedded in N\u2010doped Graphitic Carbon for Catalytic Transfer Hydrogenation of Biomass\u2010derived Furfural"],"prefix":"10.1002","volume":"16","author":[{"given":"Jun","family":"Wu","sequence":"first","affiliation":[{"name":"School of Materials Science &amp; Engineering Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials Shaanxi University of Science &amp; Technology  Xi' an Shaanxi 710021 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xinyue","family":"Yan","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials Shaanxi University of Science &amp; Technology  Xi' an Shaanxi 710021 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wenrui","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials Shaanxi University of Science &amp; Technology  Xi' an Shaanxi 710021 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ming","family":"Jin","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials Shaanxi University of Science &amp; Technology  Xi' an Shaanxi 710021 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yuhang","family":"Xie","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials Shaanxi University of Science &amp; Technology  Xi' an Shaanxi 710021 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chengbing","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials Shaanxi University of Science &amp; Technology  Xi' an Shaanxi 710021 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2021,8,25]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"crossref","first-page":"6440","DOI":"10.1021\/acscatal.1c00699","volume":"11","author":"Yang Y.-S.","year":"2021","journal-title":"ACS Catal."},{"key":"e_1_2_7_2_1","doi-asserted-by":"crossref","first-page":"8788","DOI":"10.1021\/acscatal.0c01900","volume":"10","author":"Lei L.","year":"2020","journal-title":"ACS Catal."},{"key":"e_1_2_7_3_1","doi-asserted-by":"crossref","first-page":"1144","DOI":"10.1039\/C5EE02666K","volume":"9","author":"Mariscal R.","year":"2016","journal-title":"Energy Environ. Sci."},{"key":"e_1_2_7_4_1","doi-asserted-by":"crossref","first-page":"11023","DOI":"10.1021\/acs.chemrev.8b00134","volume":"118","author":"Chen S.","year":"2018","journal-title":"Chem. Rev."},{"key":"e_1_2_7_5_1","doi-asserted-by":"crossref","first-page":"2121","DOI":"10.1021\/acscatal.7b03795","volume":"8","author":"Wang H.-J.","year":"2018","journal-title":"ACS Catal."},{"key":"e_1_2_7_6_1","doi-asserted-by":"crossref","first-page":"128693","DOI":"10.1016\/j.cej.2021.128693","volume":"414","author":"Pirmoradi M.","year":"2021","journal-title":"Chem. Eng. J."},{"key":"e_1_2_7_7_1","doi-asserted-by":"crossref","first-page":"227","DOI":"10.1016\/j.apcatb.2016.10.038","volume":"203","author":"Wu J.","year":"2017","journal-title":"Appl. Catal. B"},{"key":"e_1_2_7_8_1","doi-asserted-by":"crossref","first-page":"721","DOI":"10.1016\/j.jcat.2020.07.013","volume":"389","author":"Mironenko R. M.","year":"2020","journal-title":"J. Catal."},{"key":"e_1_2_7_9_1","doi-asserted-by":"crossref","first-page":"1711","DOI":"10.1016\/S1872-2067(18)63110-9","volume":"39","author":"Gao F.-F.","year":"2018","journal-title":"Chin. J. Catal."},{"key":"e_1_2_7_10_1","doi-asserted-by":"crossref","first-page":"4183","DOI":"10.1039\/C5GC01462J","volume":"17","author":"Fang R.-Q.","year":"2015","journal-title":"Green Chem."},{"key":"e_1_2_7_11_1","doi-asserted-by":"crossref","first-page":"106221","DOI":"10.1016\/j.catcom.2020.106221","volume":"149","author":"Weerachawanasak P.","year":"2021","journal-title":"Catal. Commun."},{"key":"e_1_2_7_12_1","doi-asserted-by":"crossref","first-page":"580","DOI":"10.1016\/j.apcatb.2015.07.006","volume":"180","author":"Taylor M. J.","year":"2016","journal-title":"Appl. Catal. B"},{"key":"e_1_2_7_13_1","doi-asserted-by":"crossref","first-page":"2822","DOI":"10.1002\/cctc.201300316","volume":"5","author":"Chen J.-Z.","year":"2013","journal-title":"ChemCatChem"},{"key":"e_1_2_7_14_1","doi-asserted-by":"crossref","first-page":"1754","DOI":"10.1021\/acscatal.5b02281","volume":"6","author":"Maligal-Ganesh R. V.","year":"2016","journal-title":"ACS Catal."},{"key":"e_1_2_7_15_1","doi-asserted-by":"crossref","first-page":"1861","DOI":"10.1039\/D0GC04029K","volume":"23","author":"Tang Y.-W.","year":"2021","journal-title":"Green Chem."},{"key":"e_1_2_7_16_1","doi-asserted-by":"crossref","first-page":"5185","DOI":"10.1002\/cssc.202001467","volume":"13","author":"Yu Z.-H.","year":"2020","journal-title":"ChemSusChem"},{"key":"e_1_2_7_17_1","doi-asserted-by":"crossref","first-page":"6621","DOI":"10.1021\/acs.chemrev.5b00203","volume":"115","author":"Wang D.","year":"2015","journal-title":"Chem. Rev."},{"key":"e_1_2_7_18_1","doi-asserted-by":"crossref","first-page":"3988","DOI":"10.1021\/acscatal.5b00586","volume":"5","author":"Gilkey M. J.","year":"2015","journal-title":"ACS Catal."},{"key":"e_1_2_7_19_1","doi-asserted-by":"crossref","first-page":"4225","DOI":"10.1021\/acs.iecr.8b00366","volume":"57","author":"Zhang Z.-H.","year":"2018","journal-title":"Ind. Eng. Chem. Res."},{"key":"e_1_2_7_20_1","doi-asserted-by":"crossref","first-page":"69","DOI":"10.1016\/j.jcat.2018.09.025","volume":"368","author":"Du J.","year":"2018","journal-title":"J. Catal."},{"key":"e_1_2_7_21_1","doi-asserted-by":"crossref","first-page":"49","DOI":"10.1016\/j.cattod.2018.07.033","volume":"324","author":"Puthiaraj P.","year":"2019","journal-title":"Catal. Today"},{"key":"e_1_2_7_22_1","doi-asserted-by":"crossref","first-page":"7722","DOI":"10.1021\/acscatal.6b02431","volume":"6","author":"Li H.","year":"2016","journal-title":"ACS Catal."},{"key":"e_1_2_7_23_1","doi-asserted-by":"crossref","first-page":"15339","DOI":"10.1021\/acssuschemeng.9b02665","volume":"7","author":"Hu D.","year":"2019","journal-title":"ACS Sustainable Chem. Eng."},{"key":"e_1_2_7_24_1","doi-asserted-by":"crossref","first-page":"3927","DOI":"10.1002\/cctc.201900481","volume":"11","author":"Durndell L. J.","year":"2019","journal-title":"ChemCatChem"},{"key":"e_1_2_7_25_1","doi-asserted-by":"crossref","first-page":"12582","DOI":"10.1002\/anie.201603198","volume":"55","author":"He L.","year":"2016","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_7_25_2","doi-asserted-by":"crossref","first-page":"12770","DOI":"10.1002\/ange.201603198","volume":"128","year":"2016","journal-title":"Angew. Chem."},{"key":"e_1_2_7_26_1","doi-asserted-by":"crossref","first-page":"3670","DOI":"10.1039\/C6CY00544F","volume":"6","author":"Li M.-M.","year":"2016","journal-title":"Catal. Sci. Technol."},{"key":"e_1_2_7_27_1","doi-asserted-by":"crossref","first-page":"2440","DOI":"10.1021\/cs400506q","volume":"3","author":"Li Z.-L.","year":"2013","journal-title":"ACS Catal."},{"key":"e_1_2_7_28_1","doi-asserted-by":"crossref","first-page":"1246","DOI":"10.1002\/cssc.201802459","volume":"12","author":"Zhang Y.-M.","year":"2019","journal-title":"ChemSusChem"},{"key":"e_1_2_7_29_1","doi-asserted-by":"crossref","first-page":"2720","DOI":"10.1021\/acscatal.7b00053","volume":"7","author":"Li Z.","year":"2017","journal-title":"ACS Catal."},{"key":"e_1_2_7_30_1","doi-asserted-by":"crossref","first-page":"4959","DOI":"10.1021\/acscatal.5b01221","volume":"5","author":"Tian H.","year":"2015","journal-title":"ACS Catal."},{"key":"e_1_2_7_31_1","doi-asserted-by":"crossref","first-page":"13592","DOI":"10.1038\/ncomms13592","volume":"8","author":"Wang H.","year":"2017","journal-title":"Nat. Commun."},{"key":"e_1_2_7_32_1","doi-asserted-by":"crossref","first-page":"371","DOI":"10.1002\/anie.201204958","volume":"52","author":"Deng D.","year":"2013","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_7_32_2","doi-asserted-by":"crossref","first-page":"389","DOI":"10.1002\/ange.201204958","volume":"125","year":"2013","journal-title":"Angew. Chem."},{"key":"e_1_2_7_33_1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.jcat.2016.04.006","volume":"340","author":"Liu L.","year":"2016","journal-title":"J. Catal."},{"key":"e_1_2_7_34_1","doi-asserted-by":"crossref","first-page":"53","DOI":"10.1016\/j.jcat.2017.09.007","volume":"355","author":"Li J.-L.","year":"2017","journal-title":"J. Catal."},{"key":"e_1_2_7_35_1","doi-asserted-by":"crossref","first-page":"1014","DOI":"10.1007\/s11426-017-9226-7","volume":"61","author":"Fu T.","year":"2018","journal-title":"Sci. China Chem."},{"key":"e_1_2_7_36_1","doi-asserted-by":"crossref","first-page":"11171","DOI":"10.1021\/acssuschemeng.0c02365","volume":"8","author":"Oliveira R.-L.","year":"2020","journal-title":"ACS Sustainable Chem. Eng."},{"key":"e_1_2_7_37_1","doi-asserted-by":"crossref","first-page":"2994","DOI":"10.1016\/j.chempr.2020.07.023","volume":"6","author":"Zhang S.","year":"2020","journal-title":"Chem"},{"key":"e_1_2_7_38_1","doi-asserted-by":"crossref","first-page":"8396","DOI":"10.1021\/acscatal.8b01404","volume":"8","author":"Li G.-Q.","year":"2018","journal-title":"ACS Catal."},{"key":"e_1_2_7_39_1","doi-asserted-by":"crossref","first-page":"3026","DOI":"10.1021\/acscatal.0c05479","volume":"11","author":"Li M.-H.","year":"2021","journal-title":"ACS Catal."},{"key":"e_1_2_7_40_1","doi-asserted-by":"crossref","first-page":"13694","DOI":"10.1039\/D0TA05322H","volume":"8","author":"Wang W.","year":"2020","journal-title":"J. Mater. Chem. A"},{"key":"e_1_2_7_41_1","doi-asserted-by":"crossref","first-page":"2415","DOI":"10.1002\/cctc.201900283","volume":"11","author":"Zhang F.-W.","year":"2019","journal-title":"ChemCatChem"},{"key":"e_1_2_7_42_1","doi-asserted-by":"crossref","first-page":"2005","DOI":"10.1039\/C7QI00492C","volume":"4","author":"Ni T.","year":"2017","journal-title":"Inorg. Chem. Front."},{"key":"e_1_2_7_43_1","doi-asserted-by":"crossref","first-page":"7890","DOI":"10.1021\/acscatal.7b02837","volume":"7","author":"Wu J.","year":"2017","journal-title":"ACS Catal."},{"key":"e_1_2_7_44_1","doi-asserted-by":"crossref","first-page":"16138","DOI":"10.1021\/acs.iecr.9b01443","volume":"58","author":"Parikh J.","year":"2019","journal-title":"Ind. Eng. Chem. Res."},{"key":"e_1_2_7_45_1","doi-asserted-by":"crossref","first-page":"2161","DOI":"10.1063\/1.371024","volume":"86","author":"Chen C.","year":"1999","journal-title":"J. Appl. Phys."},{"key":"e_1_2_7_46_1","doi-asserted-by":"crossref","first-page":"838","DOI":"10.1149\/2.0231409jes","volume":"161","author":"Liu J.","year":"2014","journal-title":"J. Electrochem. Soc."},{"key":"e_1_2_7_47_1","doi-asserted-by":"crossref","first-page":"16087","DOI":"10.1039\/C5NR03484A","volume":"7","author":"Lyth S. M.","year":"2015","journal-title":"Nanoscale"},{"key":"e_1_2_7_48_1","doi-asserted-by":"crossref","first-page":"1322","DOI":"10.1021\/acssuschemeng.6b01677","volume":"5","author":"Cai B.","year":"2017","journal-title":"ACS Sustainable Chem. Eng."},{"key":"e_1_2_7_49_1","unstructured":"\u00a0"},{"key":"e_1_2_7_50_2","doi-asserted-by":"crossref","first-page":"5714","DOI":"10.1039\/C7GC02648J","volume":"19","author":"Yang H.-H.","year":"2017","journal-title":"Green Chem."},{"key":"e_1_2_7_51_2","doi-asserted-by":"crossref","first-page":"102421","DOI":"10.1016\/j.isci.2021.102421","volume":"24","author":"Yan K.","year":"2021","journal-title":"iScience"},{"key":"e_1_2_7_52_1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1002\/anie.201410930","volume":"54","author":"Deng J.","year":"2015","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_7_52_2","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1002\/ange.201410930","volume":"127","year":"2015","journal-title":"Angew. Chem."},{"key":"e_1_2_7_53_1","doi-asserted-by":"crossref","first-page":"287","DOI":"10.1016\/j.rser.2017.04.013","volume":"77","author":"Tang X.","year":"2017","journal-title":"Renewable Sustainable Energy Rev."},{"key":"e_1_2_7_54_1","doi-asserted-by":"crossref","first-page":"74","DOI":"10.1006\/jcat.1997.1901","volume":"173","author":"Waal J. C.","year":"1998","journal-title":"J. Catal."},{"key":"e_1_2_7_55_1","doi-asserted-by":"crossref","first-page":"1339","DOI":"10.1002\/cssc.201600089","volume":"9","author":"Li J.","year":"2016","journal-title":"ChemSusChem"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202100727","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/asia.202100727","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.202100727","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T14:36:16Z","timestamp":1759934176000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.202100727"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,8,25]]},"references-count":58,"journal-issue":{"issue":"20","published-print":{"date-parts":[[2021,10,18]]}},"alternative-id":["10.1002\/asia.202100727"],"URL":"https:\/\/doi.org\/10.1002\/asia.202100727","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,8,25]]},"assertion":[{"value":"2021-06-30","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2021-08-25","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}