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Therefore, it is necessary to design an innovative approach to enhance the degree of phosphidation in the material using crystal defects. Here, oxygen\u2010vacancy iron oxide\/iron foam (Ov\u2010Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>\/IF) was firstly prepared by generating oxygen vacancy in\u2005situ in an iron foam through heating in vacuum conditions. Subsequently, FeP\/IF was formed by phosphating Ov\u2010Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>\/IF. Under the effects of oxygen vacancies, oxygen\u2010vacancy iron oxide could be completely phosphatized to produce more active sites on the surface of the material. This, in turn, could result in a catalyst with exceptional hydrogen evolution activity. Thus, the successful fabrication of FeP\/IF demonstrated in this work provides an effective and feasible way for the preparation of other high\u2010efficiency catalysts.<\/jats:p>","DOI":"10.1002\/asia.202100937","type":"journal-article","created":{"date-parts":[[2021,9,10]],"date-time":"2021-09-10T11:29:08Z","timestamp":1631273348000},"page":"3604-3609","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Promoting the Phosphidation Process using an Oxygen Vacancy Precursor for Efficient Hydrogen Evolution Reaction"],"prefix":"10.1002","volume":"16","author":[{"given":"Xiaoxiao","family":"Li","sequence":"first","affiliation":[{"name":"College of Rare Earth Jiangxi University of Science and Technology  Ganzhou 341000 P. R. China"},{"name":"Faculty of Materials Metallurgy and Chemistry Jiangxi University of Science and Technology  Ganzhou 341000 P. R. 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