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Recently, metal layers incorporating molecular chiral cavities, obtained by electroreduction of a metal source in the simultaneous presence of a non\u2010ionic surfactant and asymmetric molecules, have been proposed for a wide range of applications, including enantioselective electroanalysis and electrosynthesis, as well as chiral separation. In contrast to this previous work, solely based on electrochemical phenomena, herein we designed and employed nanostructured chiral encoded Pt\u2212Ir alloys, supported on high surface area nickel foams, as heterogeneous catalysts for the asymmetric hydrogenation of aromatic ketones. Fine\u2010tuning the experimental conditions allows achieving very high enantioselectivity (&gt;80%), combined with improved catalyst stability.<\/jats:p>","DOI":"10.1002\/asia.202100966","type":"journal-article","created":{"date-parts":[[2021,8,20]],"date-time":"2021-08-20T09:40:30Z","timestamp":1629452430000},"page":"3345-3353","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Heterogeneous Enantioselective Catalysis with Chiral Encoded Mesoporous Pt\u2212Ir Films Supported on Ni Foam"],"prefix":"10.1002","volume":"16","author":[{"given":"Sunpet","family":"Assavapanumat","sequence":"first","affiliation":[{"name":"School of Energy Science and Engineering School of Molecular Science and Engineering Frontier Research Center (FRC) Nanocatalysts and Nanomaterials for Sustainable Energy and Environment Research Network of NANOTEC Vidyasirimedhi Institute of Science and Technology (VISTEC)  21210 Rayong 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