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Thus, even though the particles are spherical, their anisotropic packing generates tailorable plasmonic dichroism. The gold nanoparticles are coated with forked ligands containing two mesogens: either two cholesterols (\u201ctwin\u201d), one cholesterol and one azobenzene (\u201cJanus\u201d), or a mixture of the two. Beside the body\u2010centered arrangement of gold nanoparticles, the structure also contains unusual two\u2010dimensionally <jats:italic>x\u2010y<\/jats:italic> dual undulated (eggbox\u2010like) smectic\u2010like layers of mesogens. Moreover, the presence of azobenzene mesogens allows the superlattice to be melted through UV\u2010induced photo\u2010isomerization; the process is reversible displaying low fatigue on repeated cycling.<\/jats:p>","DOI":"10.1002\/asia.202200057","type":"journal-article","created":{"date-parts":[[2022,2,22]],"date-time":"2022-02-22T08:53:22Z","timestamp":1645520002000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Self\u2010assembly of Gold Nanoparticles into an Adjustable Plasmonic 3D Lattice using Janus\u2010type Forked Mesogenic Ligands"],"prefix":"10.1002","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5697-3288","authenticated-orcid":false,"given":"Yang\u2010yang","family":"Zhao","sequence":"first","affiliation":[{"name":"State Key Laboratory for Mechanical Behaviour of Materials, Shaanxi International Research Center for Soft Matter Xi'an Jiaotong University  Xi'an 710049 P. R. 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