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Nevertheless, its practical application is hindered by volume expansion during the lithiation process and low electrical conductivity, resulting in rapid capacity decay. Herein, we designed a core\u2010shell structured nitrogen\u2010doped carbon\u2010encapsulated ordered mesoporous SiO<jats:sub>x<\/jats:sub> composite (SiO<jats:sub>x<\/jats:sub>@NC) using 3\u2010aminophenol\u2010formaldehyde (3\u2010AF) as carbon and nitrogen precursor, tetraethyl orthosilicate (TEOS) as the silica precursor, and cationic surfactant cetyltrimethylammonium bromide (C<jats:sub>16<\/jats:sub>TAB) as the mesoporous template. The obtained composite electrode not only can effectively reduce the volume expansion, but also can effectively improve electronic conductivity and further enhance the charge and ion transfer kinetics. Benefiting from the unique structural merits, the obtained SiO<jats:sub>x<\/jats:sub>@NC\u20102 delivers a high reversible capacity of 602.4\u2005mAh\u2009g<jats:sup>\u22121<\/jats:sup> at 0.1\u2005A\u2009g<jats:sup>\u22121<\/jats:sup> after 100\u2005cycles and long\u2010term cyclability (maintain 426.1\u2005mAh\u2009g<jats:sup>\u22121<\/jats:sup> over 1000\u2005cycles at 1\u2005A\u2009g<jats:sup>\u22121<\/jats:sup>).<\/jats:p>","DOI":"10.1002\/asia.202200440","type":"journal-article","created":{"date-parts":[[2022,6,24]],"date-time":"2022-06-24T22:44:04Z","timestamp":1656110644000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Nitrogen\u2010Doped Carbon\u2010Encapsulated Ordered Mesoporous SiO<sub>x<\/sub> as Anode for High\u2010Performance Lithium\u2010Ion Batteries"],"prefix":"10.1002","volume":"17","author":[{"given":"Yang","family":"Ling","sequence":"first","affiliation":[{"name":"School of Environmental and Chemical Engineering Shanghai University  200444 Shanghai P.\u2005R. 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