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The blue ECL of <jats:bold>Pt1<\/jats:bold>\/S<jats:sub>2<\/jats:sub>O<jats:sub>8<\/jats:sub><jats:sup>2\u2212<\/jats:sup> coreactant system in N,N\u2019\u2010dimethylformamide was found to be 46\u2005times higher than that of the Ru(bpy)<jats:sup>2+<\/jats:sup>\/S<jats:sub>2<\/jats:sub>O<jats:sub>8<\/jats:sub><jats:sup>2\u2212<\/jats:sup> system or 30\u2005times higher than that of the 9,10\u2010diphenylanthracene\/S<jats:sub>2<\/jats:sub>O<jats:sub>8<\/jats:sub><jats:sup>2\u2212<\/jats:sup> system. The unprecedented high ECL quantum efficiencies were caused by the cyclic generation of monomer excited states through collisional interactions of <jats:bold>Pt1<\/jats:bold> molecules with the electrode at an elevated frequency. The ECL is tunable from bright blue to pure white by simply changing the solvent from N,N\u2019\u2010dimethylformamide to dichloromethane. 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