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We report herein an efficient La<jats:sub>2<\/jats:sub>CuO<jats:sub>4<\/jats:sub> perovskite catalyst for one\u2010step oxidation of benzene using hydrogen peroxide under mild conditions. The catalyst was characterized using XRD, TEM, XPS, TG\u2010DTA, and other advanced techniques. The one\u2010pot hydroxylation reaction carried out at 60\u2009\u00b0C under optimum reaction conditions in the presence of catalytic material shows benzene to phenol transformation with 51% conversion with &gt;99% selectivity with 65 percent peroxide efficiency, respectively. The influence of reaction conditions such as temperature, amount of oxidant, reaction time and mode of addition of the oxidant was crucial in selectivity optimization.<\/jats:p>","DOI":"10.1002\/asia.202200788","type":"journal-article","created":{"date-parts":[[2022,10,10]],"date-time":"2022-10-10T21:35:12Z","timestamp":1665437712000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["La\u2212Cu based heterogeneous perovskite catalyst for highly selective benzene hydroxylation under mild conditions"],"prefix":"10.1002","volume":"17","author":[{"given":"Pawan","family":"Kumar","sequence":"first","affiliation":[{"name":"Catalysis and Inorganic Chemistry Division CSIR-National Chemical Laboratory  Dr. Homi Bhabha Road 411008 Pune Maharashtra India"},{"name":"Academy of Scientific and Innovative Research (AcSIR)  201002 Ghaziabad 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