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Among the various transition metals, iron has drawn huge attention due to its cost effectiveness, range of stable oxidation states, Lewis acidic property and releatively less toxicity. Iron complexes have exhibited an efficient catalytic activity towards the cross\u2010coupling reaction using organomagnesium, organolithium and organozinc reagent. Organoboron compounds are also engaged as a coupling partner for Fe catalysed C\u2212C bond forming reactions. Over the last two decades\u2019 various iron catalysed C\u2212C bond forming reactions have been developed. This review will summarize the chronological development in this research area along with challenges appearing especially in the past decade.<\/jats:p>","DOI":"10.1002\/asia.202200836","type":"journal-article","created":{"date-parts":[[2022,10,11]],"date-time":"2022-10-11T13:49:08Z","timestamp":1665496148000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Iron Catalysis: A New Horizon Towards Organoboron\u2010mediated C\u2212C Cross\u2010coupling"],"prefix":"10.1002","volume":"17","author":[{"given":"Suparna","family":"Mondal","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology  721302 Kharagpur India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kanak","family":"Kanti Das","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology  721302 Kharagpur India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4720-1224","authenticated-orcid":false,"given":"Santanu","family":"Panda","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology  721302 Kharagpur India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,11,2]]},"reference":[{"key":"e_1_2_9_1_1","unstructured":"\u00a0"},{"key":"e_1_2_9_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/3527606548"},{"key":"e_1_2_9_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900206p"},{"key":"e_1_2_9_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/9781119275602"},{"key":"e_1_2_9_5_2","doi-asserted-by":"crossref","DOI":"10.1007\/978-3-319-13054-5","volume-title":"Synthesis and Application of Organoboron Compounds, Springer","author":"Fern\u00e1ndez E.","year":"2015"},{"key":"e_1_2_9_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201510027"},{"key":"e_1_2_9_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b01410"},{"key":"e_1_2_9_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b06629"},{"key":"e_1_2_9_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201904761"},{"key":"e_1_2_9_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202002573"},{"key":"e_1_2_9_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0OB01721C"},{"key":"e_1_2_9_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC06460B"},{"key":"e_1_2_9_13_2","first-page":"e202100092","volume":"11","author":"Das K. 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