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The \u201cRu\u2010amino state\u201d is highly active for catalytic transfer hydrogenation of various aldehydes using formic acid as the hydrogen source resulting in a range of primary alcohols. On the other hand, the \u201cRu\u2010amido state\u201d is active for the acceptorless dehydrogenation of alcohols to yield carboxylate salts or ketones. The reactions can be carried out in air without an inert atmosphere and the products can be purified by simple extraction without the use of any chromatographic techniques. A range of functional groups which include electron\u2010rich and deficient (hetero)arenes and alkenes, alkynes, halides, esters, cyano, and nitro groups, are all well tolerated, indicating excellent chemoselectivity for transfer hydrogenation.<\/jats:p>","DOI":"10.1002\/asia.202200883","type":"journal-article","created":{"date-parts":[[2022,9,19]],"date-time":"2022-09-19T12:28:41Z","timestamp":1663590521000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Acceptorless Dehydrogenation of Alcohols and Transfer Hydrogenation of Aldehydes in Water Using a Single Bifunctional, Bistate, Water\u2010soluble Ruthenium Catalyst"],"prefix":"10.1002","volume":"17","author":[{"given":"Susanta","family":"Hazra","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology  Delhi, Hauz Khas New Delhi 110016 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