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Thus, it is one of the most challenging projects to activate the abundant dinitrogen through metal\u2010free systems under mild conditions. Here, we demonstrate a proof\u2010of\u2010concept study on the catalytic hydrogenation of dinitrogen (with activation energy as low as 15.3\u2005kcal\u2009mol<jats:sup>\u22121<\/jats:sup>) initiated by a dual Lewis acid (DLA) via density functional theory (DFT) calculations. In addition, such a DLA could be also used to activate a series of small molecules including carbon dioxide, formaldehyde, N\u2010ethylenemethylamine, and acetonitrile. It is found that aromaticity plays an important role in stabilizing intermediates and products. 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