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NBB\u20101 is a two\u2010dimensional zinc metal\u2010organic framework constructed from 2\u2010aminoterephthalate (NH<jats:sub>2<\/jats:sub>\u2212H<jats:sub>2<\/jats:sub>BDC) and 2,2\u2032\u2010bipyridine\u20105\u2010carboxylate (HBPC) by solvothermal method. The replacement efficiency of Pd(II) to Zn(II) is up to 72% after only 24\u2005hours, which is beneficial to the catalytic application. Pd\/NBB\u20101 with a low loading of 2\u2005mol% works efficiently in the 1,4\u2010addition reaction of arylboronic acids with \u03b1,\u03b2\u2010unsaturated ketones in air, and its catalytic activity keeps unchanged after 3 reaction cycles. This work provides a new strategy to effectively prepare supported noble metal\/MOF catalysts, which would further increase the practical applications of metal\u2010organic frameworks.<\/jats:p>","DOI":"10.1002\/asia.202201096","type":"journal-article","created":{"date-parts":[[2022,11,22]],"date-time":"2022-11-22T10:09:55Z","timestamp":1669111795000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Construction of a MOF\u2010Supported Palladium Catalyst via Metal Metathesis"],"prefix":"10.1002","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8756-9635","authenticated-orcid":false,"given":"Chenglong","family":"Liang","sequence":"first","affiliation":[{"name":"College of Chemistry and Materials Engineering Wenzhou University, Chashan University Town  Wenzhou Zhejiang Province 325035 P. R. 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