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The crystal structures of all compounds have been determined using single\u2010crystal X\u2010ray diffraction (SCXRD). A study of the magnetic susceptibility in the range 1.77\u2013300\u2005K has shown that magnetic properties of the [Cu(tda)<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>] and [Cu(tda)<jats:sub>2<\/jats:sub>Br<jats:sub>2<\/jats:sub>] complexes match those of 1D chains of antiferromagnetically\u2010coupled Cu<jats:sup>2+<\/jats:sup> ions. The intrachain interaction <jats:italic>J<\/jats:italic> in [Cu(tda)<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>] turns out to be \u223c1.2 times weaker than in its bromide analogue. In its turn, [Cu(tda)<jats:sub>2<\/jats:sub>(C<jats:sub>2<\/jats:sub>N<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>] exhibits <jats:italic>J<\/jats:italic> being an order of magnitude smaller and of the opposite ferromagnetic sign. Halogen bonding (HB) between adjacent complexes is much stronger than the H\u2010bonds or \u03c0\u2010\u03c0 interactions between tda ligands according to the DFT calculations.<\/jats:p>","DOI":"10.1002\/asia.202201200","type":"journal-article","created":{"date-parts":[[2023,1,11]],"date-time":"2023-01-11T10:49:22Z","timestamp":1673434162000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Halogen Bonding Channels for Magnetic Exchange in Cu(II) Complexes with 2,5\u2010Di(methylthio)\u20101,3,4\u2010thiadiazole"],"prefix":"10.1002","volume":"18","author":[{"given":"Ludmila G.","family":"Lavrenova","sequence":"first","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS  3 acad. 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